Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)6: [Ti(CO)4(S2CNR2)] -

Robert E. Jilek, Giovanna Tripepi, Eugenijus Urnezius, William W. Brennessel, Victor G. Young, John E. Ellis

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Oxidation of [Ti(CO)6]2- by thiuram disulfides, (R2NCS2)2, affords the first isolable mononuclear six-coordinate titanium(0) carbonyls, [Ti(CO)4(S 2CNR2)]-, which have unusual trigonal prismatic geometries and chemical and spectral properties that are remarkably similar to those of the 18-electron and seven-coordinate anion [Ti(CO)45-C5H5)]-.

Original languageEnglish (US)
Pages (from-to)2639-2641
Number of pages3
JournalChemical Communications
Issue number25
DOIs
StatePublished - Jan 1 2007

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