Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)6: [Ti(CO)4(S2CNR2)] -

Robert E. Jilek; Giovanna Tripepi; Eugenijus Urnezius; William W. Brennessel; Victor G. Young; John E. Ellis

doi:10.1039/b700808b

Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)₆: [Ti(CO)₄(S₂CNR₂)] ^-

Robert E. Jilek, Giovanna Tripepi, Eugenijus Urnezius, William W. Brennessel, Victor G. Young, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Oxidation of [Ti(CO)₆]^2- by thiuram disulfides, (R₂NCS₂)₂, affords the first isolable mononuclear six-coordinate titanium(0) carbonyls, [Ti(CO)₄(S ₂CNR₂)]^-, which have unusual trigonal prismatic geometries and chemical and spectral properties that are remarkably similar to those of the 18-electron and seven-coordinate anion [Ti(CO)₄(η ⁵-C₅H₅)]^-.

Original language	English (US)
Pages (from-to)	2639-2641
Number of pages	3
Journal	Chemical Communications
Issue number	25
DOIs	https://doi.org/10.1039/b700808b
State	Published - 2007

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title = "Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)6: [Ti(CO)4(S2CNR2)] -",

abstract = "Oxidation of [Ti(CO)6]2- by thiuram disulfides, (R2NCS2)2, affords the first isolable mononuclear six-coordinate titanium(0) carbonyls, [Ti(CO)4(S 2CNR2)]-, which have unusual trigonal prismatic geometries and chemical and spectral properties that are remarkably similar to those of the 18-electron and seven-coordinate anion [Ti(CO)4(η 5-C5H5)]-.",

author = "Jilek, {Robert E.} and Giovanna Tripepi and Eugenijus Urnezius and Brennessel, {William W.} and Young, {Victor G.} and Ellis, {John E.}",

year = "2007",

doi = "10.1039/b700808b",

language = "English (US)",

pages = "2639--2641",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "25",

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TY - JOUR

T1 - Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)6

T2 - [Ti(CO)4(S2CNR2)] -

AU - Jilek, Robert E.

AU - Tripepi, Giovanna

AU - Urnezius, Eugenijus

AU - Brennessel, William W.

AU - Young, Victor G.

AU - Ellis, John E.

PY - 2007

Y1 - 2007

N2 - Oxidation of [Ti(CO)6]2- by thiuram disulfides, (R2NCS2)2, affords the first isolable mononuclear six-coordinate titanium(0) carbonyls, [Ti(CO)4(S 2CNR2)]-, which have unusual trigonal prismatic geometries and chemical and spectral properties that are remarkably similar to those of the 18-electron and seven-coordinate anion [Ti(CO)4(η 5-C5H5)]-.

AB - Oxidation of [Ti(CO)6]2- by thiuram disulfides, (R2NCS2)2, affords the first isolable mononuclear six-coordinate titanium(0) carbonyls, [Ti(CO)4(S 2CNR2)]-, which have unusual trigonal prismatic geometries and chemical and spectral properties that are remarkably similar to those of the 18-electron and seven-coordinate anion [Ti(CO)4(η 5-C5H5)]-.

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U2 - 10.1039/b700808b

DO - 10.1039/b700808b

M3 - Article

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SN - 1359-7345

SP - 2639

EP - 2641

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)₆: [Ti(CO)₄(S₂CNR₂)] ^-

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