Z-selective ring-opening metathesis polymerization of 3-substituted cyclooctenes by monoaryloxide pyrrolide imido alkylidene (MAP) catalysts of molybdenum and Tungsten

Keyphrases

• Imido 100%
• Tungsten 100%
• Cyclooctatetraene 100%
• Molybdenum 100%
• Alkylidene 100%
• Z-selectivity 100%
• Selective Ring Opening 100%
• Ring-opening Copolymerization (ROCOP) 100%
• Poly-3 66%
• 1-pentene 66%
• Polymerization Rate 66%
• 3-methyl-1 66%
• Methyl 33%
• Disubstituted 33%
• Room Temperature 33%
• Polymerized 33%
• Proton 33%
• Polymer Structure 33%
• Metallacyclobutane 33%
• Phenyl 33%
• Metallacycles 33%
• Apparent Rate Constant 33%
• Steric Factor 33%
• Mo-N 33%
• Trigonal Bipyramidal 33%
• NMR Timescale 33%

Chemistry

• Ring Opening Metathesis Polymerisation 100%
• Molybdenum 100%
• Polymerization 100%
• Histamine 100%
• NMR Spectroscopy 50%
• Ambient Reaction Temperature 50%
• Methyl Group 50%
• Metallacycle 50%
• Ring-Opening Metathesis Polymerization 50%
• formation 50%