Vinylalumination of activated carbonyl compounds

P. Veeraraghavan Ramachandran; M. Venkat Ram Reddy; Michael T. Rudd

doi:10.1016/S0040-4039(98)02504-0

Vinylalumination of activated carbonyl compounds

P. Veeraraghavan Ramachandran, M. Venkat Ram Reddy, Michael T. Rudd

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

[α-(Ethoxycarbonyl)vinyl]diisobutylaluminum and its β-methyl and - phenyl analogs react with activated ketones, such as α-keto esters, α-acyl cyanides, and α-acetylenic ketones to provide the corresponding α- hydroxyalkenylated products in high yields.

Original language	English (US)
Pages (from-to)	627-630
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	4
DOIs	https://doi.org/10.1016/S0040-4039(98)02504-0
State	Published - Jan 22 1999

Bibliographical note

Funding Information:
The financial assistance from the Purdue Borane Research Fund is gratefully

Keywords

Acetylenic ketones
Acyl cyanides
Vinylalumination
α-keto esters

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10.1016/S0040-4039(98)02504-0

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title = "Vinylalumination of activated carbonyl compounds",

abstract = "[α-(Ethoxycarbonyl)vinyl]diisobutylaluminum and its β-methyl and - phenyl analogs react with activated ketones, such as α-keto esters, α-acyl cyanides, and α-acetylenic ketones to provide the corresponding α- hydroxyalkenylated products in high yields.",

keywords = "Acetylenic ketones, Acyl cyanides, Vinylalumination, α-keto esters",

author = "Ramachandran, {P. Veeraraghavan} and Reddy, {M. Venkat Ram} and Rudd, {Michael T.}",

note = "Funding Information: The financial assistance from the Purdue Borane Research Fund is gratefully",

year = "1999",

month = jan,

day = "22",

doi = "10.1016/S0040-4039(98)02504-0",

language = "English (US)",

volume = "40",

pages = "627--630",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Vinylalumination of activated carbonyl compounds

AU - Ramachandran, P. Veeraraghavan

AU - Reddy, M. Venkat Ram

AU - Rudd, Michael T.

N1 - Funding Information: The financial assistance from the Purdue Borane Research Fund is gratefully

PY - 1999/1/22

Y1 - 1999/1/22

N2 - [α-(Ethoxycarbonyl)vinyl]diisobutylaluminum and its β-methyl and - phenyl analogs react with activated ketones, such as α-keto esters, α-acyl cyanides, and α-acetylenic ketones to provide the corresponding α- hydroxyalkenylated products in high yields.

AB - [α-(Ethoxycarbonyl)vinyl]diisobutylaluminum and its β-methyl and - phenyl analogs react with activated ketones, such as α-keto esters, α-acyl cyanides, and α-acetylenic ketones to provide the corresponding α- hydroxyalkenylated products in high yields.

KW - Acetylenic ketones

KW - Acyl cyanides

KW - Vinylalumination

KW - α-keto esters

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UR - http://www.scopus.com/inward/citedby.url?scp=0033593294&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(98)02504-0

DO - 10.1016/S0040-4039(98)02504-0

M3 - Article

AN - SCOPUS:0033593294

SN - 0040-4039

VL - 40

SP - 627

EP - 630

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 4

ER -

Vinylalumination of activated carbonyl compounds

Abstract

Bibliographical note

Keywords

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