Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

Kristen A. Thoreson; Kristopher McNeill

doi:10.1039/c0dt01532f

Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

Kristen A. Thoreson, Kristopher McNeill

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Dechlorination reactions at sp² C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

Original language	English (US)
Pages (from-to)	1646-1648
Number of pages	3
Journal	Dalton Transactions
Volume	40
Issue number	8
DOIs	https://doi.org/10.1039/c0dt01532f
State	Published - Feb 28 2011

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10.1039/c0dt01532f

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title = "Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex",

abstract = "Dechlorination reactions at sp2 C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.",

author = "Thoreson, \{Kristen A.\} and Kristopher McNeill",

year = "2011",

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doi = "10.1039/c0dt01532f",

language = "English (US)",

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pages = "1646--1648",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

AU - Thoreson, Kristen A.

AU - McNeill, Kristopher

PY - 2011/2/28

Y1 - 2011/2/28

N2 - Dechlorination reactions at sp2 C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

AB - Dechlorination reactions at sp2 C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

UR - https://www.scopus.com/pages/publications/79951523581

UR - https://www.scopus.com/inward/citedby.url?scp=79951523581&partnerID=8YFLogxK

U2 - 10.1039/c0dt01532f

DO - 10.1039/c0dt01532f

M3 - Article

C2 - 21264430

AN - SCOPUS:79951523581

SN - 1477-9226

VL - 40

SP - 1646

EP - 1648

JO - Dalton Transactions

JF - Dalton Transactions

IS - 8

ER -

Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

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