Unusual alkylidene ligands: Synthesis and structure of the cyclopentadienylidene complex [(η5-C5H5)Ta(NEt2) 2(=C5H4)]

Paula M. Briggs; Victor G. Young; David E. Wigley

doi:10.1039/a608402h

Unusual alkylidene ligands: Synthesis and structure of the cyclopentadienylidene complex [(η⁵-C⁵H⁵)Ta(NEt₂) ₂(=C₅H₄)]

Paula M. Briggs, Victor G. Young, David E. Wigley

Chemistry (Twin Cities)

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Abstract

The unique alkylidene complex [(η⁵-C₅H₅)Ta-(NEt₂) ₂(=C₅H₄)] 2 is prepared in low yield from the reaction of [(η⁵-C₅H₅)Ta(NEt₂) ₂Cl₂] 1 with 2 equiv. of MeLi and is fully characterised including an X-ray structural determination.

Original language	English (US)
Pages (from-to)	791-792
Number of pages	2
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/a608402h
State	Published - 1997

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title = "Unusual alkylidene ligands: Synthesis and structure of the cyclopentadienylidene complex [(η5-C5H5)Ta(NEt2) 2(=C5H4)]",

abstract = "The unique alkylidene complex [(η5-C5H5)Ta-(NEt2) 2(=C5H4)] 2 is prepared in low yield from the reaction of [(η5-C5H5)Ta(NEt2) 2Cl2] 1 with 2 equiv. of MeLi and is fully characterised including an X-ray structural determination.",

author = "Briggs, {Paula M.} and Young, {Victor G.} and Wigley, {David E.}",

year = "1997",

doi = "10.1039/a608402h",

language = "English (US)",

pages = "791--792",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Unusual alkylidene ligands

T2 - Synthesis and structure of the cyclopentadienylidene complex [(η5-C5H5)Ta(NEt2) 2(=C5H4)]

AU - Briggs, Paula M.

AU - Young, Victor G.

AU - Wigley, David E.

PY - 1997

Y1 - 1997

N2 - The unique alkylidene complex [(η5-C5H5)Ta-(NEt2) 2(=C5H4)] 2 is prepared in low yield from the reaction of [(η5-C5H5)Ta(NEt2) 2Cl2] 1 with 2 equiv. of MeLi and is fully characterised including an X-ray structural determination.

AB - The unique alkylidene complex [(η5-C5H5)Ta-(NEt2) 2(=C5H4)] 2 is prepared in low yield from the reaction of [(η5-C5H5)Ta(NEt2) 2Cl2] 1 with 2 equiv. of MeLi and is fully characterised including an X-ray structural determination.

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DO - 10.1039/a608402h

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Unusual alkylidene ligands: Synthesis and structure of the cyclopentadienylidene complex [(η⁵-C⁵H⁵)Ta(NEt₂) ₂(=C₅H₄)]

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