Unprecedented (μ-1,1-Peroxo)diferric Structure for the Ambiphilic Orange Peroxo Intermediate of the Nonheme N-Oxygenase CmlI

Keyphrases

• Non-heme 100%
• Peroxo 100%
• Ambiphilic 100%
• N-oxygenase 100%
• Peroxo Intermediates 100%
• Resonance Raman 60%
• Aryl 60%
• X-ray Absorption Spectroscopy 60%
• Diiron 40%
• Nitro 40%
• Arylamines 40%
• Active Sites 40%
• Diiron Cluster 40%
• Biosynthetic Pathway 20%
• Glutamate 20%
• Dioxygen 20%
• Isotopically Labeled 20%
• Model Complex 20%
• Electrophilic 20%
• Nucleophilic 20%
• Core Structure 20%
• Raman Studies 20%
• Peroxo Ligands 20%
• Spectroscopic Characterization 20%
• Binding Geometry 20%
• Histidine 20%
• Two-electron 20%
• Refined Structure 20%
• Spectroscopic Analysis 20%
• Spectroscopy Raman 20%
• Nitroso 20%
• N-hydroxylation 20%
• Mixed Metal 20%
• Biomimetic Complexes 20%
• Asymmetric Vibration 20%
• Scatterer 20%
• Labeled Water 20%
• Active Oxidants 20%
• Fe-O Bond 20%
• O-atom 20%
• Antibiotic Chloramphenicol 20%
• Metal Models 20%
• Absorption Resonance 20%

Chemistry

• Oxygenase 100%
• X Ray Absorption Spectroscopy 100%
• Sweet Orange 100%
• Chemistry 33%
• Dioxygen 33%
• Biomimetics 33%
• Glutamate Residue 33%
• Antimicrobial Agent 33%
• Amine 33%
• Chloramphenicol 33%
• Biosynthesis 33%
• Histidine 33%
• hydroxylation 33%