Unique characteristics of ionic liquids comprised of long-chain cations and anions: A new physical insight

Chiranjib Banerjee; Sarthak Mandal; Surajit Ghosh; Jagannath Kuchlyan; Niloy Kundu; Nilmoni Sarkar

doi:10.1021/jp4015405

Unique characteristics of ionic liquids comprised of long-chain cations and anions: A new physical insight

Chiranjib Banerjee
, Sarthak Mandal
, Surajit Ghosh
, Jagannath Kuchlyan
, Niloy Kundu
, Nilmoni Sarkar

Physics and Astronomy (Twin Cities)

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

We have designed a unique class of surface active ionic liquids (SAILs) and utilized them to prepare IL-in-oil microemulsions as well as large unilamellar vesicles (LUVs). The IL-in-oil microemulsions were characterized by a phase behavior study, regular swelling behavior, and also by spectral shift of coumarin-480 probe molecules. The LUVs were characterized by dynamic light scattering and transmission electron microscope measurements. Our work opens up the possibility of creating a huge number of IL-in-oil microemulsions as well as LUVs simply by replacing the cation of NaAOT with a long chain cation.

Original language	English (US)
Pages (from-to)	3927-3934
Number of pages	8
Journal	Journal of Physical Chemistry B
Volume	117
Issue number	14
DOIs	https://doi.org/10.1021/jp4015405
State	Published - Apr 11 2013

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abstract = "We have designed a unique class of surface active ionic liquids (SAILs) and utilized them to prepare IL-in-oil microemulsions as well as large unilamellar vesicles (LUVs). The IL-in-oil microemulsions were characterized by a phase behavior study, regular swelling behavior, and also by spectral shift of coumarin-480 probe molecules. The LUVs were characterized by dynamic light scattering and transmission electron microscope measurements. Our work opens up the possibility of creating a huge number of IL-in-oil microemulsions as well as LUVs simply by replacing the cation of NaAOT with a long chain cation.",

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AU - Banerjee, Chiranjib

AU - Mandal, Sarthak

AU - Ghosh, Surajit

AU - Kuchlyan, Jagannath

AU - Kundu, Niloy

AU - Sarkar, Nilmoni

PY - 2013/4/11

Y1 - 2013/4/11

N2 - We have designed a unique class of surface active ionic liquids (SAILs) and utilized them to prepare IL-in-oil microemulsions as well as large unilamellar vesicles (LUVs). The IL-in-oil microemulsions were characterized by a phase behavior study, regular swelling behavior, and also by spectral shift of coumarin-480 probe molecules. The LUVs were characterized by dynamic light scattering and transmission electron microscope measurements. Our work opens up the possibility of creating a huge number of IL-in-oil microemulsions as well as LUVs simply by replacing the cation of NaAOT with a long chain cation.

AB - We have designed a unique class of surface active ionic liquids (SAILs) and utilized them to prepare IL-in-oil microemulsions as well as large unilamellar vesicles (LUVs). The IL-in-oil microemulsions were characterized by a phase behavior study, regular swelling behavior, and also by spectral shift of coumarin-480 probe molecules. The LUVs were characterized by dynamic light scattering and transmission electron microscope measurements. Our work opens up the possibility of creating a huge number of IL-in-oil microemulsions as well as LUVs simply by replacing the cation of NaAOT with a long chain cation.

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ER -

Unique characteristics of ionic liquids comprised of long-chain cations and anions: A new physical insight

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