Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

Pavlo V. Solntsev, Jared R. Sabin, Samantha J. Dammer, Nikolay N. Gerasimchuk, Victor N. Nemykin

Research output: Contribution to journalArticlepeer-review

53 Scopus citations

Abstract

Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

Original languageEnglish (US)
Pages (from-to)6581-6583
Number of pages3
JournalChemical Communications
Volume46
Issue number35
DOIs
StatePublished - Sep 21 2010

PubMed: MeSH publication types

  • Journal Article

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