Unambiguous determination of the ¹³C and ¹H NMR stereosequence assignments of polylactide using high-resolution solution NMR spectroscopy

Keyphrases

• High-resolution 100%
• Polylactide 100%
• 1H nuclear Magnetic Resonance (1H NMR) 100%
• 13C NMR 100%
• Solution NMR Spectroscopy 100%
• Stereosequence 100%
• Stereocenters 50%
• 13C NMR Spectra 33%
• C-terminus 33%
• 1H NMR Spectra 33%
• Lactic Acid Unit 33%
• Pairwise Relationship 33%
• Ring-opening Polymerization 16%
• NMR Spectroscopy 16%
• Physical Properties 16%
• Polymer Chain 16%
• Hydroxyl Group 16%
• NMR Spectra 16%
• Tetrad 16%
• Non-degenerate 16%
• NMR Experiments 16%
• Biodegradable Polyesters 16%
• NMR Techniques 16%
• Two-dimensional NMR 16%
• Lactide Polymerization 16%
• Lactic Acid 16%
• Stereoselectivity 16%
• Statistical Probability 16%
• Peak Assignment 16%
• Selective Isotopic Labeling 16%
• 2D HetCOR-NMR 16%
• Cyclic Dimer 16%
• New Catalysts 16%
• Carboxylic Groups 16%

Chemistry

• NMR Spectroscopy 100%
• 1H NMR Spectroscopy 100%
• Solution NMR 100%
• 13C NMR Spectroscopy 100%
• Polylactide 100%
• Lactic Acid 50%
• 1H NMR Spectrum 33%
• 13C NMR Spectrum 33%
• Chemical Kinetics Characteristics 16%
• Ring Opening Polymerisation 16%
• Hydroxyl Group 16%
• NMR Spectrum 16%
• Polymer Chain 16%
• Two-Dimensional NMR 16%
• Stereoselectivity 16%
• Polymerization 16%
• Heteronuclear Correlation Spectroscopy 16%
• dimer 16%
• Catalyst 16%
• Peptide 16%