Trityltitanium complexes. X-ray structural characterization of [Ti(CO)4{η5-C(4-C6H4R) 3}]- (R = H, OCH3)1

Paul J. Fischer; Kateri A. Ahrendt; Victor G Young; John E Ellis

doi:10.1021/om970832e

Trityltitanium complexes. X-ray structural characterization of [Ti(CO)₄{η⁵-C(4-C₆H₄R) ₃}]^- (R = H, OCH₃)¹

Paul J. Fischer, Kateri A. Ahrendt, Victor G Young, John E Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Reactions of [Ti(CO)₆]^2- and chlorotriphenyl-methane or chlorotris(4-methoxyphenyl)methane provide the first examples of trityltitanium complexes. These have been shown by IR, NMR, and single-crystal X-ray structural characterizations to have the molecular formula [Ti(CO)₄{η⁵-C(4-C₆H₄R) ₃}]^- (R = H, OCH₃).

Original language	English (US)
Pages (from-to)	13-15
Number of pages	3
Journal	Organometallics
Volume	17
Issue number	1
DOIs	https://doi.org/10.1021/om970832e
State	Published - Jan 5 1998

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title = "Trityltitanium complexes. X-ray structural characterization of [Ti(CO)4{η5-C(4-C6H4R) 3}]- (R = H, OCH3)1",

abstract = "Reactions of [Ti(CO)6]2- and chlorotriphenyl-methane or chlorotris(4-methoxyphenyl)methane provide the first examples of trityltitanium complexes. These have been shown by IR, NMR, and single-crystal X-ray structural characterizations to have the molecular formula [Ti(CO)4{η5-C(4-C6H4R) 3}]- (R = H, OCH3).",

author = "Fischer, {Paul J.} and Ahrendt, {Kateri A.} and Young, {Victor G} and Ellis, {John E}",

year = "1998",

month = jan,

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doi = "10.1021/om970832e",

language = "English (US)",

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T1 - Trityltitanium complexes. X-ray structural characterization of [Ti(CO)4{η5-C(4-C6H4R) 3}]- (R = H, OCH3)1

AU - Fischer, Paul J.

AU - Ahrendt, Kateri A.

AU - Young, Victor G

AU - Ellis, John E

PY - 1998/1/5

Y1 - 1998/1/5

N2 - Reactions of [Ti(CO)6]2- and chlorotriphenyl-methane or chlorotris(4-methoxyphenyl)methane provide the first examples of trityltitanium complexes. These have been shown by IR, NMR, and single-crystal X-ray structural characterizations to have the molecular formula [Ti(CO)4{η5-C(4-C6H4R) 3}]- (R = H, OCH3).

AB - Reactions of [Ti(CO)6]2- and chlorotriphenyl-methane or chlorotris(4-methoxyphenyl)methane provide the first examples of trityltitanium complexes. These have been shown by IR, NMR, and single-crystal X-ray structural characterizations to have the molecular formula [Ti(CO)4{η5-C(4-C6H4R) 3}]- (R = H, OCH3).

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Trityltitanium complexes. X-ray structural characterization of [Ti(CO)₄{η⁵-C(4-C₆H₄R) ₃}]^- (R = H, OCH₃)¹

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