Tris(amino)boranes: The Effect of Angle Strain on Hybridization

Jack E. Richman, N. C. Yang, Leah L. Andersen

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

The four tris(amino)boranes represented by structure 1 with ethylene and/or trimethylene bridges have been prepared. Predictions that the smallest member of this series, 10-bora-1,4,7-triazatricyclo[5.2.1.04,10]decane, would be highly strained were supported by the observation that this compound exists only as a tight dimer. 11 -Bora-1,4,7-triazatricyclo[5.3.1.04,11]undecane is dimeric in solution but monomeric in the gas phase. The X-ray crystal structure and properties of 13-bora-1,5,9-triazatricyclo [7.3.1.05,13]tridecane show that it has a stable planar BN3 aray.

Original languageEnglish (US)
Pages (from-to)5790-5792
Number of pages3
JournalJournal of the American Chemical Society
Volume102
Issue number18
DOIs
StatePublished - Aug 1980

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