Tricarbonyl(chlorodiphenylstannyl){η5-[2-(dimethylamino) ethyl]cyclopenta-dienyl}molybdenum

Paul J. Fischer; Kristina M. Krohn; Victor G. Young

doi:10.1107/S1600536809014329

Tricarbonyl(chlorodiphenylstannyl){η⁵-[2-(dimethylamino) ethyl]cyclopenta-dienyl}molybdenum

Chemistry (Twin Cities)

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Abstract

Reaction of the tricarbon-yl{ν⁵-[2-(dimethyl-amino)eth-yl] cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C6H5)2Cl(C9H14N)(CO)3], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo - Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.

Original language	English (US)
Pages (from-to)	m558-m559
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	5
DOIs	https://doi.org/10.1107/S1600536809014329
State	Published - 2009

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10.1107/S1600536809014329

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title = "Tricarbonyl(chlorodiphenylstannyl)\{η5-[2-(dimethylamino) ethyl]cyclopenta-dienyl\}molybdenum",

abstract = "Reaction of the tricarbon-yl\{ν5-[2-(dimethyl-amino)eth-yl] cyclo-penta-dien-yl\}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C6H5)2Cl(C9H14N)(CO)3], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo - Sn bond length [2.7584 (5) {\AA}] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.",

author = "Fischer, \{Paul J.\} and Krohn, \{Kristina M.\} and Young, \{Victor G.\}",

year = "2009",

doi = "10.1107/S1600536809014329",

language = "English (US)",

volume = "65",

pages = "m558--m559",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Tricarbonyl(chlorodiphenylstannyl){η5-[2-(dimethylamino) ethyl]cyclopenta-dienyl}molybdenum

AU - Fischer, Paul J.

AU - Krohn, Kristina M.

AU - Young, Victor G.

PY - 2009

Y1 - 2009

N2 - Reaction of the tricarbon-yl{ν5-[2-(dimethyl-amino)eth-yl] cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C6H5)2Cl(C9H14N)(CO)3], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo - Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.

AB - Reaction of the tricarbon-yl{ν5-[2-(dimethyl-amino)eth-yl] cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C6H5)2Cl(C9H14N)(CO)3], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo - Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.

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U2 - 10.1107/S1600536809014329

DO - 10.1107/S1600536809014329

M3 - Article

C2 - 21583791

AN - SCOPUS:66749181812

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VL - 65

SP - m558-m559

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Tricarbonyl(chlorodiphenylstannyl){η⁵-[2-(dimethylamino) ethyl]cyclopenta-dienyl}molybdenum

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