Tricarbonyl(chlorodiphenylstannyl){η5-[2-(dimethylamino) ethyl]cyclopenta-dienyl}molybdenum

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Abstract

Reaction of the tricarbon-yl{ν5-[2-(dimethyl-amino)eth-yl] cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C6H5)2Cl(C9H14N)(CO)3], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo - Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.

Original languageEnglish (US)
Pages (from-to)m558-m559
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
StatePublished - 2009

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