Abstract
Reaction of the tricarbon-yl{ν5-[2-(dimethyl-amino)eth-yl] cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C6H5)2Cl(C9H14N)(CO)3], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo - Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.
Original language | English (US) |
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Pages (from-to) | m558-m559 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 65 |
Issue number | 5 |
DOIs | |
State | Published - 2009 |