Trapping of a Reactive Tetraruthenlum Imido Cluster with Diphenylacetylene

Margaret L. Blohm; Wayne L Gladfelter

doi:10.1021/om00136a036

Trapping of a Reactive Tetraruthenlum Imido Cluster with Diphenylacetylene

Margaret L. Blohm, Wayne L Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Diphenylacetylene traps the intermediate imido cluster formed during the protonation of [Ru₄N-(CO)₁₂]^-. Structural characterization of the new cluster Ru₄(NH)(PhCCPh)(CO)₁₁revealed the first example of a tetrabridging imido ligand.

Original language	English (US)
Pages (from-to)	1049-1051
Number of pages	3
Journal	Organometallics
Volume	5
Issue number	5
DOIs	https://doi.org/10.1021/om00136a036
State	Published - Jan 1 1986

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title = "Trapping of a Reactive Tetraruthenlum Imido Cluster with Diphenylacetylene",

abstract = "Diphenylacetylene traps the intermediate imido cluster formed during the protonation of [Ru4N-(CO)12]-. Structural characterization of the new cluster Ru4(NH)(PhCCPh)(CO)11revealed the first example of a tetrabridging imido ligand.",

author = "Blohm, {Margaret L.} and Gladfelter, {Wayne L}",

year = "1986",

month = jan,

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T1 - Trapping of a Reactive Tetraruthenlum Imido Cluster with Diphenylacetylene

AU - Blohm, Margaret L.

AU - Gladfelter, Wayne L

PY - 1986/1/1

Y1 - 1986/1/1

N2 - Diphenylacetylene traps the intermediate imido cluster formed during the protonation of [Ru4N-(CO)12]-. Structural characterization of the new cluster Ru4(NH)(PhCCPh)(CO)11revealed the first example of a tetrabridging imido ligand.

AB - Diphenylacetylene traps the intermediate imido cluster formed during the protonation of [Ru4N-(CO)12]-. Structural characterization of the new cluster Ru4(NH)(PhCCPh)(CO)11revealed the first example of a tetrabridging imido ligand.

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Trapping of a Reactive Tetraruthenlum Imido Cluster with Diphenylacetylene

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