Transcyclopalladation on silica gel

Jessica R. Lamb, Valeria A. Stepanova, Irina P. Smoliakova

Research output: Contribution to journalArticlepeer-review

4 Scopus citations


A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF 3CO2H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.

Original languageEnglish (US)
Pages (from-to)202-207
Number of pages6
StatePublished - 2013
Externally publishedYes

Bibliographical note

Funding Information:
The authors acknowledge financial support from ND EPSCoR through NSF Grant No. EPS-0-0184442.


  • Cyclopalladated complexes
  • Cyclopalladated ligand exchange
  • Reactions on silica gel
  • Transcyclopalladation


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