Transcyclopalladation on silica gel

Jessica R. Lamb; Valeria A. Stepanova; Irina P. Smoliakova

doi:10.1016/j.poly.2013.01.030

Transcyclopalladation on silica gel

Jessica R. Lamb, Valeria A. Stepanova, Irina P. Smoliakova

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF ₃CO₂H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.

Original language	English (US)
Pages (from-to)	202-207
Number of pages	6
Journal	Polyhedron
Volume	53
DOIs	https://doi.org/10.1016/j.poly.2013.01.030
State	Published - 2013
Externally published	Yes

Bibliographical note

Funding Information:
The authors acknowledge financial support from ND EPSCoR through NSF Grant No. EPS-0-0184442.

Keywords

Cyclopalladated complexes
Cyclopalladated ligand exchange
Reactions on silica gel
Transcyclopalladation

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10.1016/j.poly.2013.01.030

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title = "Transcyclopalladation on silica gel",

abstract = "A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF 3CO2H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.",

keywords = "Cyclopalladated complexes, Cyclopalladated ligand exchange, Reactions on silica gel, Transcyclopalladation",

author = "Lamb, {Jessica R.} and Stepanova, {Valeria A.} and Smoliakova, {Irina P.}",

note = "Funding Information: The authors acknowledge financial support from ND EPSCoR through NSF Grant No. EPS-0-0184442.",

year = "2013",

doi = "10.1016/j.poly.2013.01.030",

language = "English (US)",

volume = "53",

pages = "202--207",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Transcyclopalladation on silica gel

AU - Lamb, Jessica R.

AU - Stepanova, Valeria A.

AU - Smoliakova, Irina P.

N1 - Funding Information: The authors acknowledge financial support from ND EPSCoR through NSF Grant No. EPS-0-0184442.

PY - 2013

Y1 - 2013

N2 - A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF 3CO2H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.

AB - A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF 3CO2H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.

KW - Cyclopalladated complexes

KW - Cyclopalladated ligand exchange

KW - Reactions on silica gel

KW - Transcyclopalladation

UR - http://www.scopus.com/inward/record.url?scp=84875428787&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84875428787&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2013.01.030

DO - 10.1016/j.poly.2013.01.030

M3 - Article

AN - SCOPUS:84875428787

VL - 53

SP - 202

EP - 207

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

Transcyclopalladation on silica gel

Abstract

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