TY - JOUR
T1 - Transcyclopalladation on silica gel
AU - Lamb, Jessica R.
AU - Stepanova, Valeria A.
AU - Smoliakova, Irina P.
PY - 2013
Y1 - 2013
N2 - A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF 3CO2H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.
AB - A possibility of transcyclopalladation on silica gel was shown using reactions of acetato- and chloro-bridged dimeric cyclopalladated complexes derived from N,N-dimethylbenzylamine with benzyl methyl sulfide, benzyl phenyl sulfide, benzyldiphenylphosphine, 8-methylquinoline and 1,3- bis(methylthiomethyl)benzene in the presence of equimolar amount of CF 3CO2H. The reaction provided the corresponding C,S-, C,N-, C,P- and S,C,S-palladacycles in 39-65% yield.
KW - Cyclopalladated complexes
KW - Cyclopalladated ligand exchange
KW - Reactions on silica gel
KW - Transcyclopalladation
UR - http://www.scopus.com/inward/record.url?scp=84875428787&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84875428787&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2013.01.030
DO - 10.1016/j.poly.2013.01.030
M3 - Article
AN - SCOPUS:84875428787
VL - 53
SP - 202
EP - 207
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
ER -