trans influences on hypervalent bonding of aryl λ3- iodanes: Their stabilities and isodesmic reactions of benziodoxolones and benziodazolones

Masahito Ochiai, Takuya Sueda, Kazunori Miyamoto, Paul Kiprof, Viktor V. Zhdankin

Research output: Contribution to journalArticlepeer-review

71 Scopus citations

Abstract

Large and small or twice moderate: Both combinations of trans influences of the substituents favor the formation of highly stable aryl λ 3-iodanes ArILL' (examples: PhI(OH)OTs and PhI(OAc)2). trans influences also seem to explain why iodosylbenzene adopts an oxo-bridged zigzag polymer structure in contrast to PhI(OH)2, which is monomeric. (Chemical Equation Presented).

Original languageEnglish (US)
Pages (from-to)8203-8206
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number48
DOIs
StatePublished - Dec 11 2006

Keywords

  • Hypervalent compounds
  • Iodine
  • Iodosylbenzene
  • Substituent effects
  • trans influence

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