Towards homoleptic naphthalenemetalates of the later transition metals: Isolation and characterization of naphthalenecobaltates(1-)

William W. Brennessel; Victor G Young; John E Ellis

doi:10.1002/anie.200602937

Towards homoleptic naphthalenemetalates of the later transition metals: Isolation and characterization of naphthalenecobaltates(1-)

William W. Brennessel, Victor G Young, John E Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Taming of the wild anions: Highly labile naphthalene complexes of formally negative-valent later transition metals have been obtained in the form of [Co(η⁴-C₁₀H₈) (η⁴-cod)] ^- (see picture; cod = 1,5-cyclooctadiene) and [Co(η⁴- C₁₀H₈)₂]^-. The latter is the first structurally authenticated homoleptic bis (naphthalene) metal anion for any d-block element and promises to be a particularly reactive synthon for the "naked" atomic cobalt anion. (Figure Presented).

Original language	English (US)
Pages (from-to)	7268-7271
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	43
DOIs	https://doi.org/10.1002/anie.200602937
State	Published - Nov 3 2006

Keywords

Alkene ligands
Arene ligands
Cobalt
Cobaltates
Subvalent compounds

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abstract = "Taming of the wild anions: Highly labile naphthalene complexes of formally negative-valent later transition metals have been obtained in the form of [Co(η4-C10H8) (η4-cod)] - (see picture; cod = 1,5-cyclooctadiene) and [Co(η4- C10H8)2]-. The latter is the first structurally authenticated homoleptic bis (naphthalene) metal anion for any d-block element and promises to be a particularly reactive synthon for the {"}naked{"} atomic cobalt anion. (Figure Presented).",

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author = "Brennessel, {William W.} and Young, {Victor G} and Ellis, {John E}",

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T1 - Towards homoleptic naphthalenemetalates of the later transition metals

T2 - Isolation and characterization of naphthalenecobaltates(1-)

AU - Brennessel, William W.

AU - Young, Victor G

AU - Ellis, John E

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N2 - Taming of the wild anions: Highly labile naphthalene complexes of formally negative-valent later transition metals have been obtained in the form of [Co(η4-C10H8) (η4-cod)] - (see picture; cod = 1,5-cyclooctadiene) and [Co(η4- C10H8)2]-. The latter is the first structurally authenticated homoleptic bis (naphthalene) metal anion for any d-block element and promises to be a particularly reactive synthon for the "naked" atomic cobalt anion. (Figure Presented).

AB - Taming of the wild anions: Highly labile naphthalene complexes of formally negative-valent later transition metals have been obtained in the form of [Co(η4-C10H8) (η4-cod)] - (see picture; cod = 1,5-cyclooctadiene) and [Co(η4- C10H8)2]-. The latter is the first structurally authenticated homoleptic bis (naphthalene) metal anion for any d-block element and promises to be a particularly reactive synthon for the "naked" atomic cobalt anion. (Figure Presented).

KW - Alkene ligands

KW - Arene ligands

KW - Cobalt

KW - Cobaltates

KW - Subvalent compounds

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Towards homoleptic naphthalenemetalates of the later transition metals: Isolation and characterization of naphthalenecobaltates(1-)

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