Toroidal nuclei of columnar lyotropic chromonic liquid crystals coexisting with an isotropic phase

  • Runa Koizumi
  • , Dmitry Golovaty
  • , Ali Alqarni
  • , Shawn W. Walker
  • , Yuriy A. Nastishin
  • , M. Carme Calderer
  • , Oleg D. Lavrentovich

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Nuclei of ordered materials emerging from the isotropic state usually show a shape topologically equivalent to a sphere; the well-known examples are crystals and nematic liquid crystal droplets. In this work, we explore experimentally and theoretically the toroidal in shape nuclei of columnar lyotropic chromonic liquid crystals coexisting with the isotropic phase. The geometry of these toroids depends strongly on concentrations of the disodium cromoglycate (DSCG) and the crowding agent, polyethylene glycol (PEG). High concentrations of DSCG and PEG result in thick toroids with small central holes, while low concentrations yield thin toroids with wide holes. The multitude of the observed shapes is explained by the balance of bending elasticity and anisotropic interfacial tension.

Original languageEnglish (US)
Pages (from-to)7258-7268
Number of pages11
JournalSoft Matter
Volume18
Issue number38
DOIs
StatePublished - Jul 29 2022

Bibliographical note

Publisher Copyright:
© 2022 The Royal Society of Chemistry.

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