Titanium dicarbollide complexes. Molecular structures of (η5-C2B9H11)(C 5Me5)TiMe and (η5-C2B9H11)(η 51-C5Me4CH2)Ti

Xiaohong Bei, Victor G. Young, Richard F. Jordan

Research output: Contribution to journalArticlepeer-review

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Abstract

X-ray structural studies establish that the titanium dicarbollide complexes (η5-C2B9H11)(C 5Me5)TiMe (4) and (η5-C2B9H11)(η 51-C5Me4CH2)Ti (5) adopt bent metallocene structures. In 4 the metallocene units are linked into chains by weak intermolecular Ti⋯H-B interactions involving B-H units that are meta to Ti within the C2B9Ti cages. The fulvene ligand in 5 is bonded in α π-η5,σ-η1-fashion.

Original languageEnglish (US)
Pages (from-to)355-358
Number of pages4
JournalOrganometallics
Volume20
Issue number2
DOIs
StatePublished - Jan 22 2001

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