TiO(OH)2 - Highly effective catalysts for optimizing CO2 desorption kinetics reducing CO2 capture cost

A new pathway

Hongbao Yao, Sam Q Toan, Liang Huang, Maohong Fan, Yujun Wang, Armistead G. Russell, Guangsheng Luo, Weiyang Fei

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The objective is to find a new pathway for significant reduction in CO2 capture energy consumption. Specifically, nanoporous TiO(OH)2 was used to realize the objective, which was desired as a catalyst to significantly accelerate the decomposition of aqueous NaHCO3, essentially CO2 desorption - the key step of Na2CO3/NaHCO3 based CO2 capture technologies from overall CO2 energy consumption perspective. Effects of several important factors on TiO(OH)2-catalyzed NaHCO3 decomposition were investigated. The quantity of CO2 generated from 0.238 mol/L NaHCO3 at 65 °C with catalyst is ∼800% of that generated without the presence of catalyst. When a 12 W vacuum pump was used for carrying the generated CO2 out of reactor, the total amount of CO2 released was improved by ∼2,500% under the given experimental conditions. No significant decrease in the catalytic effect of TiO(OH)2 was observed after five cyclic CO2 activated tests. In addition, characterizations with in-situ Fourier transform infrared spectroscopy, thermal gravity analysis and Brunauer-Emmett-Teller of TiO(OH)2 indicate that TiO(OH)2 is quite stable. The discovery in this research could inspire scientists' interests in starting to focus on a new pathway instead of making huge effort or investment in designing high-capacity but expensive CO2 sorbent for developing practical or cost-effective CO2 technologies.

Original languageEnglish (US)
Article number2943
JournalScientific reports
Volume7
Issue number1
DOIs
StatePublished - Dec 1 2017

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Technology
Costs and Cost Analysis
Gravitation
Fourier Transform Infrared Spectroscopy
Vacuum
Hot Temperature
Research

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TiO(OH)2 - Highly effective catalysts for optimizing CO2 desorption kinetics reducing CO2 capture cost : A new pathway. / Yao, Hongbao; Toan, Sam Q; Huang, Liang; Fan, Maohong; Wang, Yujun; Russell, Armistead G.; Luo, Guangsheng; Fei, Weiyang.

In: Scientific reports, Vol. 7, No. 1, 2943, 01.12.2017.

Research output: Contribution to journalArticle

Yao, Hongbao ; Toan, Sam Q ; Huang, Liang ; Fan, Maohong ; Wang, Yujun ; Russell, Armistead G. ; Luo, Guangsheng ; Fei, Weiyang. / TiO(OH)2 - Highly effective catalysts for optimizing CO2 desorption kinetics reducing CO2 capture cost : A new pathway. In: Scientific reports. 2017 ; Vol. 7, No. 1.
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