[Ti(CO)4(η3-BH4)]- and [Ti(CO)4(η5-C4H4N)]-: The first zerovalent metal complexes containing η3-borohydride and pyrrolyl ligands

Paul J. Fischer; Victor G. Young; John E. Ellis

doi:10.1002/(SICI)1521-3773(20000103)39:1<189::AID-ANIE189>3.0.CO;2-O

[Ti(CO)₄(η³-BH₄)]^- and [Ti(CO)₄(η⁵-C₄H₄N)]-: The first zerovalent metal complexes containing η³-borohydride and pyrrolyl ligands

Paul J. Fischer, Victor G. Young, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Tridentate binding of BH₄^- to a zero-valent metal center was found for the first time in [Ti(CO)₄(η³-BH₄)]^- (shown in the picture), which was obtained from the reaction of the carbonyl metalate anion [Ti(CO)₆]^2- with BH₃·THF. Displacement of the unusually labile BH₄^- anion by a pyrrolyl anion provided the first metal(o) pyrrolyl complex [Ti(CO)₄(η⁵-C₄H₄N)]^- .

Original language	English (US)
Pages (from-to)	189-191
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	1
DOIs	https://doi.org/10.1002/(SICI)1521-3773(20000103)39:1<189::AID-ANIE189>3.0.CO;2-O
State	Published - Jan 3 2000

Keywords

Boron
Carbonyl complexes
Titanium

Access

10.1002/(SICI)1521-3773(20000103)39:1<189::AID-ANIE189>3.0.CO;2-O

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title = "[Ti(CO)4(η3-BH4)]- and [Ti(CO)4(η5-C4H4N)]-: The first zerovalent metal complexes containing η3-borohydride and pyrrolyl ligands",

abstract = "Tridentate binding of BH4- to a zero-valent metal center was found for the first time in [Ti(CO)4(η3-BH4)]- (shown in the picture), which was obtained from the reaction of the carbonyl metalate anion [Ti(CO)6]2- with BH3·THF. Displacement of the unusually labile BH4- anion by a pyrrolyl anion provided the first metal(o) pyrrolyl complex [Ti(CO)4(η5-C4H4N)]- .",

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T1 - [Ti(CO)4(η3-BH4)]- and [Ti(CO)4(η5-C4H4N)]-

T2 - The first zerovalent metal complexes containing η3-borohydride and pyrrolyl ligands

AU - Fischer, Paul J.

AU - Young, Victor G.

AU - Ellis, John E.

PY - 2000/1/3

Y1 - 2000/1/3

N2 - Tridentate binding of BH4- to a zero-valent metal center was found for the first time in [Ti(CO)4(η3-BH4)]- (shown in the picture), which was obtained from the reaction of the carbonyl metalate anion [Ti(CO)6]2- with BH3·THF. Displacement of the unusually labile BH4- anion by a pyrrolyl anion provided the first metal(o) pyrrolyl complex [Ti(CO)4(η5-C4H4N)]- .

AB - Tridentate binding of BH4- to a zero-valent metal center was found for the first time in [Ti(CO)4(η3-BH4)]- (shown in the picture), which was obtained from the reaction of the carbonyl metalate anion [Ti(CO)6]2- with BH3·THF. Displacement of the unusually labile BH4- anion by a pyrrolyl anion provided the first metal(o) pyrrolyl complex [Ti(CO)4(η5-C4H4N)]- .

KW - Boron

KW - Carbonyl complexes

KW - Titanium

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