Thin robust anion exchange membranes for fuel cell applications

Himanshu Sarode; Melissa A. Vandiver; Ye Liu; Ashley M. Maes; Tara P. Pandey; S. Piril Ertem; Tsunghan Tsai; Bingzi Zhang; Daniel C. Herbst; Gerrick E. Lindberg; Ying Lung Steven Tse; Sönke Seifert; Vito Di Noto; E. Bryan Coughlin; Yushan Yan; Gregory A. Voth; Thomas A. Witten; Daniel Knauss; Matthew W. Liberatore; Andrew M. Herring

doi:10.1149/06403.1185ecst

Thin robust anion exchange membranes for fuel cell applications

Himanshu Sarode, Melissa A. Vandiver, Ye Liu, Ashley M. Maes, Tara P. Pandey, S. Piril Ertem, Tsunghan Tsai, Bingzi Zhang, Daniel C. Herbst, Gerrick E. Lindberg, Ying Lung Steven Tse, Sönke Seifert, Vito Di Noto, E. Bryan Coughlin, Yushan Yan, Gregory A. Voth, Thomas A. Witten, Daniel Knauss, Matthew W. Liberatore, Andrew M. Herring

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Scopus citations

Abstract

Extensive transport and modeling studies have been performed on a series of polymers based on the benzyltrimethylamonium cations. We have created a realistic reactive model of solvated hydroxide that has interesting properties in the polymer matrix. In ordered diblock polymers we have strong theoretical evidence for a heterogeneous distribution of water across the channel. Fluoride is used as a non-reactive surrogate for hydroxide to increase the computational efficiency of transport calculations that can be performed. In addition to these studies we are discovering new base stable processable robust polymer backbones and cations. These bulky cations seem to dramatically affect the transport properties of the anions showing a VTF rather than an Arrhenius behavior with temperature.

Original language	English (US)
Title of host publication	Polymer Electrolyte Fuel Cells 14
Editors	K. Shinohara, S. R. Narayanan, K. Swider-Lyons, A. Weber, C. Coutanceau, R. Mantz, H. A. Gasteiger, D. Jones, M. Edmundson, S. Mitsushima, V. Ramani, Y. Meas, T. Fuller, H. Uchida, F. N. Buchi, K. A. Perry, T. J. Schmidt, J. M. Fenton, P. Strasser
Publisher	Electrochemical Society Inc.
Pages	1185-1194
Number of pages	10
Edition	3
ISBN (Electronic)	9781607685395
DOIs	https://doi.org/10.1149/06403.1185ecst
State	Published - 2014
Externally published	Yes
Event	14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting - Cancun, Mexico Duration: Oct 5 2014 → Oct 9 2014

Publication series

Name	ECS Transactions
Number	3
Volume	64
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Other

Other	14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting
Country/Territory	Mexico
City	Cancun
Period	10/5/14 → 10/9/14

Bibliographical note

Publisher Copyright:
© The Electrochemical Society.

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1149/06403.1185ecst

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Sarode, H., Vandiver, M. A., Liu, Y., Maes, A. M., Pandey, T. P., Ertem, S. P., Tsai, T., Zhang, B., Herbst, D. C., Lindberg, G. E., Tse, Y. L. S., Seifert, S., Di Noto, V., Coughlin, E. B., Yan, Y., Voth, G. A., Witten, T. A., Knauss, D., Liberatore, M. W., & Herring, A. M. (2014). Thin robust anion exchange membranes for fuel cell applications. In K. Shinohara, S. R. Narayanan, K. Swider-Lyons, A. Weber, C. Coutanceau, R. Mantz, H. A. Gasteiger, D. Jones, M. Edmundson, S. Mitsushima, V. Ramani, Y. Meas, T. Fuller, H. Uchida, F. N. Buchi, K. A. Perry, T. J. Schmidt, J. M. Fenton, & P. Strasser (Eds.), Polymer Electrolyte Fuel Cells 14 (3 ed., pp. 1185-1194). (ECS Transactions; Vol. 64, No. 3). Electrochemical Society Inc.. https://doi.org/10.1149/06403.1185ecst

Thin robust anion exchange membranes for fuel cell applications. / Sarode, Himanshu; Vandiver, Melissa A.; Liu, Ye et al.
Polymer Electrolyte Fuel Cells 14. ed. / K. Shinohara; S. R. Narayanan; K. Swider-Lyons; A. Weber; C. Coutanceau; R. Mantz; H. A. Gasteiger; D. Jones; M. Edmundson; S. Mitsushima; V. Ramani; Y. Meas; T. Fuller; H. Uchida; F. N. Buchi; K. A. Perry; T. J. Schmidt; J. M. Fenton; P. Strasser. 3. ed. Electrochemical Society Inc., 2014. p. 1185-1194 (ECS Transactions; Vol. 64, No. 3).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Sarode, H, Vandiver, MA, Liu, Y, Maes, AM, Pandey, TP, Ertem, SP, Tsai, T, Zhang, B, Herbst, DC, Lindberg, GE, Tse, YLS, Seifert, S, Di Noto, V, Coughlin, EB, Yan, Y, Voth, GA, Witten, TA, Knauss, D, Liberatore, MW & Herring, AM 2014, Thin robust anion exchange membranes for fuel cell applications. in K Shinohara, SR Narayanan, K Swider-Lyons, A Weber, C Coutanceau, R Mantz, HA Gasteiger, D Jones, M Edmundson, S Mitsushima, V Ramani, Y Meas, T Fuller, H Uchida, FN Buchi, KA Perry, TJ Schmidt, JM Fenton & P Strasser (eds), Polymer Electrolyte Fuel Cells 14. 3 edn, ECS Transactions, no. 3, vol. 64, Electrochemical Society Inc., pp. 1185-1194, 14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting, Cancun, Mexico, 10/5/14. https://doi.org/10.1149/06403.1185ecst

Sarode H, Vandiver MA, Liu Y, Maes AM, Pandey TP, Ertem SP et al. Thin robust anion exchange membranes for fuel cell applications. In Shinohara K, Narayanan SR, Swider-Lyons K, Weber A, Coutanceau C, Mantz R, Gasteiger HA, Jones D, Edmundson M, Mitsushima S, Ramani V, Meas Y, Fuller T, Uchida H, Buchi FN, Perry KA, Schmidt TJ, Fenton JM, Strasser P, editors, Polymer Electrolyte Fuel Cells 14. 3 ed. Electrochemical Society Inc. 2014. p. 1185-1194. (ECS Transactions; 3). doi: 10.1149/06403.1185ecst

Sarode, Himanshu ; Vandiver, Melissa A. ; Liu, Ye et al. / Thin robust anion exchange membranes for fuel cell applications. Polymer Electrolyte Fuel Cells 14. editor / K. Shinohara ; S. R. Narayanan ; K. Swider-Lyons ; A. Weber ; C. Coutanceau ; R. Mantz ; H. A. Gasteiger ; D. Jones ; M. Edmundson ; S. Mitsushima ; V. Ramani ; Y. Meas ; T. Fuller ; H. Uchida ; F. N. Buchi ; K. A. Perry ; T. J. Schmidt ; J. M. Fenton ; P. Strasser. 3. ed. Electrochemical Society Inc., 2014. pp. 1185-1194 (ECS Transactions; 3).

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abstract = "Extensive transport and modeling studies have been performed on a series of polymers based on the benzyltrimethylamonium cations. We have created a realistic reactive model of solvated hydroxide that has interesting properties in the polymer matrix. In ordered diblock polymers we have strong theoretical evidence for a heterogeneous distribution of water across the channel. Fluoride is used as a non-reactive surrogate for hydroxide to increase the computational efficiency of transport calculations that can be performed. In addition to these studies we are discovering new base stable processable robust polymer backbones and cations. These bulky cations seem to dramatically affect the transport properties of the anions showing a VTF rather than an Arrhenius behavior with temperature.",

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ER -

Thin robust anion exchange membranes for fuel cell applications

Abstract

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