Thermoplastic polyurethane elastomers from bio-based poly(δ- decalactone) diols

Bio-based poly(δ-decalactone) is an amorphous, low glass transition temperature (T_g) material and it is an aliphatic polyester (Martello et al., ACS Macro Lett., 2011) that can be utilized as a soft segment in thermoplastic polyurethanes (TPU). We describe the synthesis and purification of low molar mass poly(δ-decalactone) diols (PdDL), as well as the synthesis and characterization of new PdDL-based TPUs. The PdDLs obtained were characterized by proton nuclear magnetic resonance (¹H-NMR) spectroscopy and matrix-assisted laser desorption ionization mass spectroscopy. Three different PdDLs were prepared and their molar masses calculated from ¹H-NMR spectroscopy were: M_n ≈ 1300, 1800 and 2700 g mol^-1. These three PdDLs were reacted with 4,4′- methylenebis(phenyl isocyanate) and two different chain extenders (1,4-butanediol and water), to synthesize polyester-based TPUs. The TPUs made from PdDLs with M_n of 1800 and 2700 exhibit good elastomeric properties and their T_g values are around -40°C. With water as chain extender urea bonds were created, which gave TPUs with higher modulus, higher stress at break and lower hysteresis. This journal is