Thermodynamic Properties of LiCL in Dimethyl Sulfoxide

William H. Smyrl, Charles W. Tobias

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

EMF measurements were performed at 25°, 30°, and 35°C on the cell Pt(s)/Li(s)/LiCl(solution in DMSO)/TlCl(s)/Tl(Hg)(l)/Pt(s) For concentrations up to 0.12M, the activity coefficients at each temperature may be represented satisfactorily by Guggenheim's extension of the Debye-Hückel equation. The partial molal Gibbs free energy, entropy and enthalpy of transfer of LiCL from DMSO to water have been calculated to be −4.93 kcal/mole, +24.8 cal/°K-mole and +2.61 kcal/mole, respectively.

Original languageEnglish (US)
Pages (from-to)33-36
Number of pages4
JournalJournal of the Electrochemical Society
Volume115
Issue number1
DOIs
StatePublished - Jan 1968

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