Thermodynamic Driving Force in the Spontaneous Formation of Inorganic Nanoparticle Solutions

Lance M. Wheeler, Nicolaas J. Kramer, Uwe R. Kortshagen

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Nanoparticles are the bridge between the molecular and the macroscopic worlds. The growing number of commercial applications for nanoparticles spans from consumer products to new frontiers of medicine and next-generation optoelectronic technology. They are most commonly deployed in the form of a colloid, or "ink", which are formulated with solvents, surfactants, and electrolytes to kinetically prevent the solid particulate phase from reaching the thermodynamically favored state of separate solid and liquid phases. In this work, we theoretically determine the thermodynamic requirements for forming a single-phase solution of spherical particles and engineer a model system to experimentally demonstrate the spontaneous formation of solutions composed of only solvent and bare inorganic nanoparticles. We show molecular interactions at the nanoparticle interface are the driving force in high-concentration nanoparticle solutions. The work establishes a regime where inorganic nanoparticles behave as molecular solutes as opposed to kinetically stable colloids, which has far-reaching implications for the future design and deployment of nanomaterial technologies.

Original languageEnglish (US)
Pages (from-to)1888-1895
Number of pages8
JournalNano Letters
Volume18
Issue number3
DOIs
StatePublished - Mar 14 2018

Fingerprint

Thermodynamics
Nanoparticles
nanoparticles
thermodynamics
Colloids
colloids
Consumer products
Molecular interactions
inks
molecular interactions
medicine
Nanostructured materials
Ink
Surface-Active Agents
Optoelectronic devices
particulates
Electrolytes
engineers
Medicine
solid phases

Keywords

  • colloidal stability
  • ligand-free
  • quantum dot
  • semiconductor nanocrystal
  • Silicon

How much support was provided by MRSEC?

  • Shared

Reporting period for MRSEC

  • Period 4

PubMed: MeSH publication types

  • Journal Article
  • Research Support, Non-U.S. Gov't

Cite this

Thermodynamic Driving Force in the Spontaneous Formation of Inorganic Nanoparticle Solutions. / Wheeler, Lance M.; Kramer, Nicolaas J.; Kortshagen, Uwe R.

In: Nano Letters, Vol. 18, No. 3, 14.03.2018, p. 1888-1895.

Research output: Contribution to journalArticle

Wheeler, Lance M. ; Kramer, Nicolaas J. ; Kortshagen, Uwe R. / Thermodynamic Driving Force in the Spontaneous Formation of Inorganic Nanoparticle Solutions. In: Nano Letters. 2018 ; Vol. 18, No. 3. pp. 1888-1895.
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