Theoretical studies on the monomeric vanadium oxides supported by ceria: the atomic structures and oxidative dehydrogenation activities

Xin Ping Wu; Juanjuan Liu; Jie Fan; Xue Qing Gong

doi:10.1039/c5ra08962j

Theoretical studies on the monomeric vanadium oxides supported by ceria: the atomic structures and oxidative dehydrogenation activities

Xin Ping Wu, Juanjuan Liu, Jie Fan, Xue Qing Gong

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The relative stabilities of different CeO₂(111)-supported VO_x are compared by calculating the phase diagrams, and a thermodynamically more stable VO₂ type monomeric species is located. Studies based on H adsorption and O vacancy formation suggest high activities of the determined VO_x (x = 2-4) species in oxidative dehydrogenation reactions.

Original language	English (US)
Pages (from-to)	52259-52263
Number of pages	5
Journal	RSC Advances
Volume	5
Issue number	64
DOIs	https://doi.org/10.1039/c5ra08962j
State	Published - 2015

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry.

Publisher link

10.1039/c5ra08962j

Find It

Find It at U of M Libraries

Cite this

@article{0e92c99b2e224fb195e7045ad1780992,

title = "Theoretical studies on the monomeric vanadium oxides supported by ceria: the atomic structures and oxidative dehydrogenation activities",

abstract = "The relative stabilities of different CeO2(111)-supported VOx are compared by calculating the phase diagrams, and a thermodynamically more stable VO2 type monomeric species is located. Studies based on H adsorption and O vacancy formation suggest high activities of the determined VOx (x = 2-4) species in oxidative dehydrogenation reactions.",

author = "Wu, \{Xin Ping\} and Juanjuan Liu and Jie Fan and Gong, \{Xue Qing\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

doi = "10.1039/c5ra08962j",

language = "English (US)",

volume = "5",

pages = "52259--52263",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "64",

}

TY - JOUR

T1 - Theoretical studies on the monomeric vanadium oxides supported by ceria

T2 - the atomic structures and oxidative dehydrogenation activities

AU - Wu, Xin Ping

AU - Liu, Juanjuan

AU - Fan, Jie

AU - Gong, Xue Qing

PY - 2015

Y1 - 2015

N2 - The relative stabilities of different CeO2(111)-supported VOx are compared by calculating the phase diagrams, and a thermodynamically more stable VO2 type monomeric species is located. Studies based on H adsorption and O vacancy formation suggest high activities of the determined VOx (x = 2-4) species in oxidative dehydrogenation reactions.

AB - The relative stabilities of different CeO2(111)-supported VOx are compared by calculating the phase diagrams, and a thermodynamically more stable VO2 type monomeric species is located. Studies based on H adsorption and O vacancy formation suggest high activities of the determined VOx (x = 2-4) species in oxidative dehydrogenation reactions.

UR - https://www.scopus.com/pages/publications/84934924932

UR - https://www.scopus.com/inward/citedby.url?scp=84934924932&partnerID=8YFLogxK

U2 - 10.1039/c5ra08962j

DO - 10.1039/c5ra08962j

M3 - Article

AN - SCOPUS:84934924932

SN - 2046-2069

VL - 5

SP - 52259

EP - 52263

JO - RSC Advances

JF - RSC Advances

IS - 64

ER -

Theoretical studies on the monomeric vanadium oxides supported by ceria: the atomic structures and oxidative dehydrogenation activities

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this