Alkali metal reduction of M2(CO)10 or M(CO) 5- (M = Mn and Re) in hexamethylphosphoramide provides the first non-cluster binary metal carbonyl trianions, M(CO)4 3-, which are characterized by their spectral and chemical properties.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - Jan 1 1975|