The road to non-heme oxoferryls and beyond

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Abstract

Oxoiron(IV) species are often implicated in the catalytic cycles of oxygen-activating non-heme iron enzymes. The paucity of suitable model complexes stimulated us to fill this void, and our synthetic efforts have afforded a number of oxoiron(IV) complexes. This Account provides a chronological perspective of the observations that contributed to the generation of the first non-heme iron(IV)-oxo complexes in high yield and summarizes their salient properties to date.

Original languageEnglish (US)
Pages (from-to)493-500
Number of pages8
JournalAccounts of Chemical Research
Volume40
Issue number7
DOIs
StatePublished - Jul 2007

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