The Planar Blatter Radical: Structural Chemistry of 1,4-Dihydrobenzo[e][1,2,4]triazin-4-yls

Piotr Kaszyński, Christos P. Constantinides, Victor G. Young

Research output: Contribution to journalArticle

27 Scopus citations

Abstract

Two planarized analogues of the prototypical Blatter radical (1), peri-annulated 1Sand 1O, are demonstrated and provide a new platform for molecular and supramolecular engineering, and for tuning electronic and magnetic properties of the radical. Planarization of 1 results in bathochromic shift to the near-IR region, greater spin delocalization, and anodic shift of the reduction potential only for 1S. Magnetization studies revealed nearly ideal paramagnetic behavior at high temperatures for both radicals 1Sand 1Owith one-dimensional ferromagnetic interaction in the former (2J=14.4 cm−1) and antiferromagnetic interactions in 1Oat low temperatures.

Original languageEnglish (US)
Pages (from-to)11149-11152
Number of pages4
JournalAngewandte Chemie - International Edition
Volume55
Issue number37
DOIs
StatePublished - Jan 1 2016

Keywords

  • magnetic properties
  • radicals
  • solid-state structure
  • structure elucidation
  • supramolecular chemistry

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