The odijk regime in slits

Douglas R. Tree, Wesley F. Reinhart, Kevin D. Dorfman

Research output: Contribution to journalArticle

32 Scopus citations

Abstract

De Gennes blob theory has been remarkably successful at describing weakly confined polymers in both slits and channels, and comparable results surround Odijks theory of deflection segments for strongly confined wormlike polymers in nanochannels. However, given the success of Odijks theory in channels, it is remarkable that there is no comprehensive theory for the simple case of a wormlike polymer strongly confined between two parallel plates. We propose such a theory by drawing inspiration from the existing literature on ideal wormlike chains in slits and Daoud and de Gennes idea of mapping a slit-confined chain to a two-dimensional chain. We postulate that the chain can be quantitatively described as a two-dimensional wormlike chain with a weak perturbation in the confining dimension due to deflection segments. By incorporating the effects of real chains, where the variable slit depth adds subtlety due to concomitant changes in the strength of excluded volume interactions, our theory predicts the existence of three distinct subregimes. We investigate the validity of our claims by performing Monte Carlo simulations of a slit-confined wormlike chain using an off-lattice implementation of the pruned-enriched Rosenbluth method. From these simulations, we find strong numerical evidence supporting our predictions, including the existence of subregimes within the Odijk regime.

Original languageEnglish (US)
Pages (from-to)3672-3684
Number of pages13
JournalMacromolecules
Volume47
Issue number11
DOIs
StatePublished - Jun 10 2014

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    Tree, D. R., Reinhart, W. F., & Dorfman, K. D. (2014). The odijk regime in slits. Macromolecules, 47(11), 3672-3684. https://doi.org/10.1021/ma500647v