The muonic He atom and a preliminary study of the 4He μ + H2 reaction

Donald J. Arseneau, Donald G. Fleming, Oleksandr Sukhorukov, Jess H. Brewer, Bruce C. Garrett, Donald G Truhlar

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Abstract

The muonic atom 4He μ has the composition α++ μ- e-, and is formed by stopping negative muons in He doped with a small amount of NH3 (or Xe). It may be regarded as a unique heavy H-atom isotope with a mass of 4.1 amu. As such, the study of its chemical reaction rates and comparison with those of the well-known light Mu atom (0.113 amu) allows unprecedented tests of kinetic isotope effects over a range of 36 in mass. As a first example, and one which is of most fundamental interest, we have begun kinetics studies of the He μ + H2 → He μ H + H reaction in the gas phase. The first measurements, at 295 K, give a rate constant of kHe μ = 4.1 ± 0.7 × 10- 16 cm3 molec- 1 s- 1. In comparison, variational transition state calculations give a value of 2.46 × 10- 16 cm3 molec- 1 s- 1, somewhat below the measurement, despite the large error bar, raising the possibility that the calculations, on an essentially exact potential energy surface, have underestimated the amount of quantum tunneling involved, even for this heavy H-atom isotope.

Original languageEnglish (US)
Pages (from-to)946-949
Number of pages4
JournalPhysica B: Condensed Matter
Volume404
Issue number5-7
DOIs
StatePublished - Apr 15 2009

Keywords

  • He μ atom
  • Heavy H-atom
  • Hydrogen
  • Kinetic isotope effects
  • Reaction rate
  • Variational TST

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