The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: Insights into a new substrate-catalyzed bimolecular pathway

Pritha Verma; Pragya Verma; Raghavan B. Sunoj

doi:10.1039/c3ob42273a

The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: Insights into a new substrate-catalyzed bimolecular pathway

Pritha Verma, Pragya Verma, Raghavan B. Sunoj

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Abstract

The first mechanistic study on the NHC-catalyzed aza-MBH reaction between cyclopentenone and N-mesylbenzaldimine using density functional theory reveals that a bimolecular mechanism, involving two molecules of benzaldimine in the proton transfer, is energetically more preferred over the conventional direct proton transfer. This journal is

Original language	English (US)
Pages (from-to)	2176-2179
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	14
DOIs	https://doi.org/10.1039/c3ob42273a
State	Published - Apr 14 2014
Externally published	Yes

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10.1039/c3ob42273a

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The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: Insights into a new substrate-catalyzed bimolecular pathway

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