The layered RuBr3-RuI3 honeycomb system

Danrui Ni; Xianghan Xu; Robert J. Cava

doi:10.1039/d3tc04718k

The layered RuBr₃-RuI₃ honeycomb system

Danrui Ni, Xianghan Xu, Robert J. Cava

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The layered RuBr₃-RuI₃ honeycomb structure solid solution was synthesized at high pressures. The crystal structures are centrosymmetric (space group R3̄) and based on honeycomb layers of spin ½ Ru³⁺. The solid solution switches from insulating to metallic between RuBr_0.75I_2.25 and RuBr_0.50I_2.50. A preliminary structure/property phase diagram is presented. Our results suggest that this solid solution may provide insight into the influence of disorder on spin-orbit-coupled quantum spin liquids.

Original language	English (US)
Pages (from-to)	4897-4903
Number of pages	7
Journal	Journal of Materials Chemistry C
Volume	12
Issue number	13
DOIs	https://doi.org/10.1039/d3tc04718k
State	Published - Mar 11 2024
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2024 The Royal Society of Chemistry

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10.1039/d3tc04718k

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title = "The layered RuBr3-RuI3 honeycomb system",

abstract = "The layered RuBr3-RuI3 honeycomb structure solid solution was synthesized at high pressures. The crystal structures are centrosymmetric (space group R{\=3}) and based on honeycomb layers of spin ½ Ru3+. The solid solution switches from insulating to metallic between RuBr0.75I2.25 and RuBr0.50I2.50. A preliminary structure/property phase diagram is presented. Our results suggest that this solid solution may provide insight into the influence of disorder on spin-orbit-coupled quantum spin liquids.",

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AU - Xu, Xianghan

AU - Cava, Robert J.

PY - 2024/3/11

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N2 - The layered RuBr3-RuI3 honeycomb structure solid solution was synthesized at high pressures. The crystal structures are centrosymmetric (space group R3̄) and based on honeycomb layers of spin ½ Ru3+. The solid solution switches from insulating to metallic between RuBr0.75I2.25 and RuBr0.50I2.50. A preliminary structure/property phase diagram is presented. Our results suggest that this solid solution may provide insight into the influence of disorder on spin-orbit-coupled quantum spin liquids.

AB - The layered RuBr3-RuI3 honeycomb structure solid solution was synthesized at high pressures. The crystal structures are centrosymmetric (space group R3̄) and based on honeycomb layers of spin ½ Ru3+. The solid solution switches from insulating to metallic between RuBr0.75I2.25 and RuBr0.50I2.50. A preliminary structure/property phase diagram is presented. Our results suggest that this solid solution may provide insight into the influence of disorder on spin-orbit-coupled quantum spin liquids.

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