The formation and molecular structure of acetylcyclopentadienylsodium-tetrahydrofuranate

Robin D. Rogers; Jerry L. Atwood; Marvin D. Rausch; David W. Macomber; William P. Hart

doi:10.1016/S0022-328X(00)86839-4

The formation and molecular structure of acetylcyclopentadienylsodium-tetrahydrofuranate

Robin D. Rogers, Jerry L. Atwood, Marvin D. Rausch, David W. Macomber, William P. Hart

Medicine - General Internal Medicine

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

Acetylcyclopentadienylsodium has been isolated in crystalline form as a THF adduct from a reaction between cyclopentadienylsodium and methyl acetate in THF solution. The product has been characterized by means of a single-crystal X-ray diffraction study. {[C₅H₄CMeO]Na·THF}_n crystallizes in the monoclinic space group P2₁/c with unit cell parameters a 6.698(3), b 16.095(4), c 10.661(3) Å, β 92.93(3)° and D_c 1.17 g cm^-3 for Z = 4. Least-squares refinement led to a final R value of 0.080 based on 661 independent observed reflections. The coordination sphere around each sodium atom consists of the oxygen atoms from two C₅H₄CMeO ligands, the oxygen atom of the THF molecule, and an ion contact pair between the sodium and the five ring carbon atoms of the C₅H₄CMeO ligand.

Original language	English (US)
Pages (from-to)	79-85
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	238
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)86839-4
State	Published - Oct 19 1982

Bibliographical note

Funding Information:
We are grateful to the U.S. National Science Foundation for support of this work.

Publisher link

10.1016/S0022-328X(00)86839-4

Find It

Find It at U of M Libraries

Cite this

@article{ec9bcafeff484cd1a96d3892e9a1da45,

title = "The formation and molecular structure of acetylcyclopentadienylsodium-tetrahydrofuranate",

abstract = "Acetylcyclopentadienylsodium has been isolated in crystalline form as a THF adduct from a reaction between cyclopentadienylsodium and methyl acetate in THF solution. The product has been characterized by means of a single-crystal X-ray diffraction study. {[C5H4CMeO]Na·THF}n crystallizes in the monoclinic space group P21/c with unit cell parameters a 6.698(3), b 16.095(4), c 10.661(3) {\AA}, β 92.93(3)° and Dc 1.17 g cm-3 for Z = 4. Least-squares refinement led to a final R value of 0.080 based on 661 independent observed reflections. The coordination sphere around each sodium atom consists of the oxygen atoms from two C5H4CMeO ligands, the oxygen atom of the THF molecule, and an ion contact pair between the sodium and the five ring carbon atoms of the C5H4CMeO ligand.",

author = "Rogers, {Robin D.} and Atwood, {Jerry L.} and Rausch, {Marvin D.} and Macomber, {David W.} and Hart, {William P.}",

note = "Funding Information: We are grateful to the U.S. National Science Foundation for support of this work.",

year = "1982",

month = oct,

day = "19",

doi = "10.1016/S0022-328X(00)86839-4",

language = "English (US)",

volume = "238",

pages = "79--85",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - The formation and molecular structure of acetylcyclopentadienylsodium-tetrahydrofuranate

AU - Rogers, Robin D.

AU - Atwood, Jerry L.

AU - Rausch, Marvin D.

AU - Macomber, David W.

AU - Hart, William P.

N1 - Funding Information: We are grateful to the U.S. National Science Foundation for support of this work.

PY - 1982/10/19

Y1 - 1982/10/19

N2 - Acetylcyclopentadienylsodium has been isolated in crystalline form as a THF adduct from a reaction between cyclopentadienylsodium and methyl acetate in THF solution. The product has been characterized by means of a single-crystal X-ray diffraction study. {[C5H4CMeO]Na·THF}n crystallizes in the monoclinic space group P21/c with unit cell parameters a 6.698(3), b 16.095(4), c 10.661(3) Å, β 92.93(3)° and Dc 1.17 g cm-3 for Z = 4. Least-squares refinement led to a final R value of 0.080 based on 661 independent observed reflections. The coordination sphere around each sodium atom consists of the oxygen atoms from two C5H4CMeO ligands, the oxygen atom of the THF molecule, and an ion contact pair between the sodium and the five ring carbon atoms of the C5H4CMeO ligand.

AB - Acetylcyclopentadienylsodium has been isolated in crystalline form as a THF adduct from a reaction between cyclopentadienylsodium and methyl acetate in THF solution. The product has been characterized by means of a single-crystal X-ray diffraction study. {[C5H4CMeO]Na·THF}n crystallizes in the monoclinic space group P21/c with unit cell parameters a 6.698(3), b 16.095(4), c 10.661(3) Å, β 92.93(3)° and Dc 1.17 g cm-3 for Z = 4. Least-squares refinement led to a final R value of 0.080 based on 661 independent observed reflections. The coordination sphere around each sodium atom consists of the oxygen atoms from two C5H4CMeO ligands, the oxygen atom of the THF molecule, and an ion contact pair between the sodium and the five ring carbon atoms of the C5H4CMeO ligand.

UR - http://www.scopus.com/inward/record.url?scp=0002130232&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0002130232&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)86839-4

DO - 10.1016/S0022-328X(00)86839-4

M3 - Article

AN - SCOPUS:0002130232

SN - 0022-328X

VL - 238

SP - 79

EP - 85

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

The formation and molecular structure of acetylcyclopentadienylsodium-tetrahydrofuranate

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this