The far-infrared Laser Magnetic Resonance spectrum of the 17OH radical: Determination of nuclear hyperfine parameters

Kenneth R. Leopold; Kenneth M. Evenson; Elizabeth R. Comben; John M. Brown

doi:10.1016/0022-2852(87)90018-X

The far-infrared Laser Magnetic Resonance spectrum of the ¹⁷OH radical: Determination of nuclear hyperfine parameters

Kenneth R. Leopold, Kenneth M. Evenson, Elizabeth R. Comben, John M. Brown

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

The far-infrared (FIR) Laser Magnetic Resonance (LMR) spectrum of the ¹⁷OH radical in the v = 0 level of the X²Π state has been studied in detail. The measurements have been analyzed and, in combination with some earlier EPR measurements, subjected to a single least-squares fit using an effective Hamiltonian. A full set of ¹⁷O nuclear hyperfine parameters has been determined. Some implications of these parameter values for the electronic wavefunction of OH are considered.

Original language	English (US)
Pages (from-to)	440-454
Number of pages	15
Journal	Journal of molecular spectroscopy
Volume	122
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(87)90018-X
State	Published - Apr 1987

Bibliographical note

Funding Information:
in part by NASA Contract

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abstract = "The far-infrared (FIR) Laser Magnetic Resonance (LMR) spectrum of the 17OH radical in the v = 0 level of the X2Π state has been studied in detail. The measurements have been analyzed and, in combination with some earlier EPR measurements, subjected to a single least-squares fit using an effective Hamiltonian. A full set of 17O nuclear hyperfine parameters has been determined. Some implications of these parameter values for the electronic wavefunction of OH are considered.",

author = "Leopold, {Kenneth R.} and Evenson, {Kenneth M.} and Comben, {Elizabeth R.} and Brown, {John M.}",

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T2 - Determination of nuclear hyperfine parameters

AU - Leopold, Kenneth R.

AU - Evenson, Kenneth M.

AU - Comben, Elizabeth R.

AU - Brown, John M.

N1 - Funding Information: in part by NASA Contract

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AB - The far-infrared (FIR) Laser Magnetic Resonance (LMR) spectrum of the 17OH radical in the v = 0 level of the X2Π state has been studied in detail. The measurements have been analyzed and, in combination with some earlier EPR measurements, subjected to a single least-squares fit using an effective Hamiltonian. A full set of 17O nuclear hyperfine parameters has been determined. Some implications of these parameter values for the electronic wavefunction of OH are considered.

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