The Effects of Atropisomerism and Porphyrin Deformation on 57 Fe Shieldings in Superstructured Hemoprotein Models

Ioannis P. Gerothanassis, Charalampos G. Kalodimos, Geoffrey E. Hawkes, Peter Haycock

Research output: Contribution to journalEditorialpeer-review

9 Scopus citations

Abstract

57 Fe NMR chemical shifts of superstructured heme model compounds have been found to be extremely sensitive to atropisomerism and deformation (ruffling) of the porphyrin geometry.

Original languageEnglish (US)
Pages (from-to)163-165
Number of pages3
JournalJournal of Magnetic Resonance
Volume131
Issue number1
DOIs
StatePublished - Mar 1998

Keywords

  • Atropisomerism
  • Fe NMR
  • Heme models
  • Porphyrin deformation

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