The effect of the concentration of ligand on the polarographic reduction waves of palladium

Robert J. Magee, William H Douglas

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

The effect of the ligand concentration on the polarographic reduction waves of the platinum metals has been studied using pyridine as the ligand and palladium as a representative of the platinum metals. The shift in the reduction peak with increase in ligand concentration is used to calculate formation constants of the complexes formed in solution. The results obtained are discussed on the basis of statistical, symmetry and d-level splitting-considerations.

Original languageEnglish (US)
Pages (from-to)261-266
Number of pages6
JournalJournal of Electroanalytical Chemistry
Volume6
Issue number4
StatePublished - Oct 1963

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