The effect of solubility on the stability of titanium(IV) arene complexes derived from hexasubstituted arenes and TiCl4

Paul Kiprof; Jun Li; Catherine L. Renish; Eddie K. Kalombo; Victor G Young

doi:10.1016/S0022-328X(00)00852-4

The effect of solubility on the stability of titanium(IV) arene complexes derived from hexasubstituted arenes and TiCl₄

Paul Kiprof, Jun Li, Catherine L. Renish, Eddie K. Kalombo, Victor G Young

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The investigation of new titaniuni(IV) hexaalkylarene complexes gave new insight into the stability of high-valent metal arene complexes. In contrast to low-valent transition metal arene complexes these complexes are in equilibrium with the free arenes. The stability of the complexes was shown to depend strongly on both the donor ability of the arene and on their solubility. This is unprecedented in transition metal arene chemistry.

Original language	English (US)
Pages (from-to)	113-118
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	620
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(00)00852-4
State	Published - Feb 15 2001

Bibliographical note

Funding Information:
This work was supported by a grant from Research Corporation. We would also like to thank the Swenson Family Foundation (Summer scholarship for CLR). and the McNair Scholar Program (Summer scholarship for EKK). We also would like to thank Professor Robert M. Carlson for helpful discussions.

Keywords

Arene complexes
High-valent
Solubility
Stability
Titanium

Publisher link

10.1016/S0022-328X(00)00852-4

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title = "The effect of solubility on the stability of titanium(IV) arene complexes derived from hexasubstituted arenes and TiCl4",

abstract = "The investigation of new titaniuni(IV) hexaalkylarene complexes gave new insight into the stability of high-valent metal arene complexes. In contrast to low-valent transition metal arene complexes these complexes are in equilibrium with the free arenes. The stability of the complexes was shown to depend strongly on both the donor ability of the arene and on their solubility. This is unprecedented in transition metal arene chemistry.",

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T1 - The effect of solubility on the stability of titanium(IV) arene complexes derived from hexasubstituted arenes and TiCl4

AU - Kiprof, Paul

AU - Li, Jun

AU - Renish, Catherine L.

AU - Kalombo, Eddie K.

AU - Young, Victor G

N1 - Funding Information: This work was supported by a grant from Research Corporation. We would also like to thank the Swenson Family Foundation (Summer scholarship for CLR). and the McNair Scholar Program (Summer scholarship for EKK). We also would like to thank Professor Robert M. Carlson for helpful discussions.

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AB - The investigation of new titaniuni(IV) hexaalkylarene complexes gave new insight into the stability of high-valent metal arene complexes. In contrast to low-valent transition metal arene complexes these complexes are in equilibrium with the free arenes. The stability of the complexes was shown to depend strongly on both the donor ability of the arene and on their solubility. This is unprecedented in transition metal arene chemistry.

KW - Arene complexes

KW - High-valent

KW - Solubility

KW - Stability

KW - Titanium

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