The Claisen Rearrangement of Iron Allyloxy Carbene Complexes

Anthony G.M. Barrett; Nancy E Carpenter

doi:10.1021/om00153a037

The Claisen Rearrangement of Iron Allyloxy Carbene Complexes

Anthony G.M. Barrett, Nancy E Carpenter

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Several cationic iron(II) allyloxy carbene complexes have been prepared from the corresponding iron vinylidenes {Fe(ή⁵-C₅H₅)(CO)[P(OCH₃)₃](C= CR¹R²}⁺X” (X =BF4, OSO₂CF₃). These compounds have been deprotonated with KH and 18-crown-6 and thermally rearranged in situ to give the corresponding γ,δ-unsatu-rated iron acyl complexes in moderate yields.

Original language	English (US)
Pages (from-to)	2249-2250
Number of pages	2
Journal	Organometallics
Volume	6
Issue number	10
DOIs	https://doi.org/10.1021/om00153a037
State	Published - Oct 1 1987
Externally published	Yes

Publisher link

10.1021/om00153a037

Find It

Find It at U of M Libraries

Cite this

@article{fa21b6d4da62488ab75d4f99bcc20f1f,

title = "The Claisen Rearrangement of Iron Allyloxy Carbene Complexes",

abstract = "Several cationic iron(II) allyloxy carbene complexes have been prepared from the corresponding iron vinylidenes {Fe(ή5-C5H5)(CO)[P(OCH3)3](C= CR1R2}+X” (X =BF4, OSO2CF3). These compounds have been deprotonated with KH and 18-crown-6 and thermally rearranged in situ to give the corresponding γ,δ-unsatu-rated iron acyl complexes in moderate yields.",

author = "Barrett, {Anthony G.M.} and Carpenter, {Nancy E}",

year = "1987",

month = oct,

day = "1",

doi = "10.1021/om00153a037",

language = "English (US)",

volume = "6",

pages = "2249--2250",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - The Claisen Rearrangement of Iron Allyloxy Carbene Complexes

AU - Barrett, Anthony G.M.

AU - Carpenter, Nancy E

PY - 1987/10/1

Y1 - 1987/10/1

N2 - Several cationic iron(II) allyloxy carbene complexes have been prepared from the corresponding iron vinylidenes {Fe(ή5-C5H5)(CO)[P(OCH3)3](C= CR1R2}+X” (X =BF4, OSO2CF3). These compounds have been deprotonated with KH and 18-crown-6 and thermally rearranged in situ to give the corresponding γ,δ-unsatu-rated iron acyl complexes in moderate yields.

AB - Several cationic iron(II) allyloxy carbene complexes have been prepared from the corresponding iron vinylidenes {Fe(ή5-C5H5)(CO)[P(OCH3)3](C= CR1R2}+X” (X =BF4, OSO2CF3). These compounds have been deprotonated with KH and 18-crown-6 and thermally rearranged in situ to give the corresponding γ,δ-unsatu-rated iron acyl complexes in moderate yields.

UR - http://www.scopus.com/inward/record.url?scp=0000722852&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000722852&partnerID=8YFLogxK

U2 - 10.1021/om00153a037

DO - 10.1021/om00153a037

M3 - Article

AN - SCOPUS:0000722852

SN - 0276-7333

VL - 6

SP - 2249

EP - 2250

JO - Organometallics

JF - Organometallics

IS - 10

ER -

The Claisen Rearrangement of Iron Allyloxy Carbene Complexes

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this