The chemistry of the group V metal carbonyls IV. Mixed metal seven-coordinate complexes

A. Davison; J. E. Ellis

doi:10.1016/S0022-328X(00)85128-1

The chemistry of the group V metal carbonyls IV. Mixed metal seven-coordinate complexes

A. Davison
, J. E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

89 Scopus citations

Abstract

The preparation of the main group mixed metal complexes (C₆H₅)₃SnM(CO)₆, (C₆H₅)₃SnM(CO)₅(C₆H₅)₃P, (C₆H₅)₃SnM(CO)₄[(C₆H₅)₂PCH₂]₂; (C₆H₅)₃PAuM(CO)₆, (C₆H₅)₃PAuM(CO)₅(C₆H₅)₃P; C₂H₅HgM(CO)₆, C₂H₅HgM(CO)₅(C₆H₅)₃P where M = V, Nb or Ta is described. The unsubstituted complexes are very prone to heterolytic cleavage in weak donor solvents. This behavior, as well as that for the phosphine substituted complexes, is discussed in relationship to the synthesis of mixed metal complexes.

Original language	English (US)
Pages (from-to)	113-130
Number of pages	18
Journal	Journal of Organometallic Chemistry
Volume	36
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)85128-1
State	Published - Mar 1 1972

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title = "The chemistry of the group V metal carbonyls IV. Mixed metal seven-coordinate complexes",

abstract = "The preparation of the main group mixed metal complexes (C6H5)3SnM(CO)6, (C6H5)3SnM(CO)5(C6H5)3P, (C6H5)3SnM(CO)4[(C6H5)2PCH2]2; (C6H5)3PAuM(CO)6, (C6H5)3PAuM(CO)5(C6H5)3P; C2H5HgM(CO)6, C2H5HgM(CO)5(C6H5)3P where M = V, Nb or Ta is described. The unsubstituted complexes are very prone to heterolytic cleavage in weak donor solvents. This behavior, as well as that for the phosphine substituted complexes, is discussed in relationship to the synthesis of mixed metal complexes.",

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T1 - The chemistry of the group V metal carbonyls IV. Mixed metal seven-coordinate complexes

AU - Davison, A.

AU - Ellis, J. E.

PY - 1972/3/1

Y1 - 1972/3/1

N2 - The preparation of the main group mixed metal complexes (C6H5)3SnM(CO)6, (C6H5)3SnM(CO)5(C6H5)3P, (C6H5)3SnM(CO)4[(C6H5)2PCH2]2; (C6H5)3PAuM(CO)6, (C6H5)3PAuM(CO)5(C6H5)3P; C2H5HgM(CO)6, C2H5HgM(CO)5(C6H5)3P where M = V, Nb or Ta is described. The unsubstituted complexes are very prone to heterolytic cleavage in weak donor solvents. This behavior, as well as that for the phosphine substituted complexes, is discussed in relationship to the synthesis of mixed metal complexes.

AB - The preparation of the main group mixed metal complexes (C6H5)3SnM(CO)6, (C6H5)3SnM(CO)5(C6H5)3P, (C6H5)3SnM(CO)4[(C6H5)2PCH2]2; (C6H5)3PAuM(CO)6, (C6H5)3PAuM(CO)5(C6H5)3P; C2H5HgM(CO)6, C2H5HgM(CO)5(C6H5)3P where M = V, Nb or Ta is described. The unsubstituted complexes are very prone to heterolytic cleavage in weak donor solvents. This behavior, as well as that for the phosphine substituted complexes, is discussed in relationship to the synthesis of mixed metal complexes.

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U2 - 10.1016/S0022-328X(00)85128-1

DO - 10.1016/S0022-328X(00)85128-1

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AN - SCOPUS:0000673683

SN - 0022-328X

VL - 36

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EP - 130

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

The chemistry of the group V metal carbonyls IV. Mixed metal seven-coordinate complexes

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