The chemistry of metal carbonyl anions. VII. Reduction of cyclopentadienylmetal carbonyls in hexamethylphosphoramide

John E. Ellis; Robert A. Faltynek; Steven G. Hentges

doi:10.1016/S0022-328X(00)98050-1

The chemistry of metal carbonyl anions. VII. Reduction of cyclopentadienylmetal carbonyls in hexamethylphosphoramide

John E. Ellis, Robert A. Faltynek, Steven G. Hentges

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The alkali metal reductions of a series of monomeric and dimeric cyclopentadienyl-substituted metal carbonyls in hexamethylphosphoramide provide principally C₅H₅V(CO)₃^2- from C₅H₅V(CO)₄, Mn(CO)₄^3- from C₅H₅Mn(CO)₃, Co(CO)₄^- from C₅H₅Co(CO)₂, and C₅H₅M(CO)_y^- from corresponding [C₅H₅M(CO)_y]₂, where M = Mo, Fe and Ni for y = 3, 2 and 1, respectively. The spectral and chemical properties of many of these reduced species are described.

Original language	English (US)
Pages (from-to)	389-396
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	120
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)98050-1
State	Published - Nov 9 1976

Bibliographical note

Funding Information:
We acknowledge support of this research by the donors of the Petroleum Research Fund, administered by the American Chemical Society. J.E.E. and R.A.F. thank the E_I_ duPont de Nemours and Co. for generous support of this research in the form of a Young Faculty Grant and a Graduate Fellowship, respectively. J.E.E. also is grateful to Prof. Robert Bergman of Caltech for a helpful discussion and disclosure of unpublished observations on the vanadium and manganese systems obtained in his laboratory_

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title = "The chemistry of metal carbonyl anions. VII. Reduction of cyclopentadienylmetal carbonyls in hexamethylphosphoramide",

abstract = "The alkali metal reductions of a series of monomeric and dimeric cyclopentadienyl-substituted metal carbonyls in hexamethylphosphoramide provide principally C5H5V(CO)32- from C5H5V(CO)4, Mn(CO)43- from C5H5Mn(CO)3, Co(CO)4- from C5H5Co(CO)2, and C5H5M(CO)y- from corresponding [C5H5M(CO)y]2, where M = Mo, Fe and Ni for y = 3, 2 and 1, respectively. The spectral and chemical properties of many of these reduced species are described.",

author = "Ellis, {John E.} and Faltynek, {Robert A.} and Hentges, {Steven G.}",

note = "Funding Information: We acknowledge support of this research by the donors of the Petroleum Research Fund, administered by the American Chemical Society. J.E.E. and R.A.F. thank the E_I_ duPont de Nemours and Co. for generous support of this research in the form of a Young Faculty Grant and a Graduate Fellowship, respectively. J.E.E. also is grateful to Prof. Robert Bergman of Caltech for a helpful discussion and disclosure of unpublished observations on the vanadium and manganese systems obtained in his laboratory_",

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AU - Ellis, John E.

AU - Faltynek, Robert A.

AU - Hentges, Steven G.

N1 - Funding Information: We acknowledge support of this research by the donors of the Petroleum Research Fund, administered by the American Chemical Society. J.E.E. and R.A.F. thank the E_I_ duPont de Nemours and Co. for generous support of this research in the form of a Young Faculty Grant and a Graduate Fellowship, respectively. J.E.E. also is grateful to Prof. Robert Bergman of Caltech for a helpful discussion and disclosure of unpublished observations on the vanadium and manganese systems obtained in his laboratory_

PY - 1976/11/9

Y1 - 1976/11/9

N2 - The alkali metal reductions of a series of monomeric and dimeric cyclopentadienyl-substituted metal carbonyls in hexamethylphosphoramide provide principally C5H5V(CO)32- from C5H5V(CO)4, Mn(CO)43- from C5H5Mn(CO)3, Co(CO)4- from C5H5Co(CO)2, and C5H5M(CO)y- from corresponding [C5H5M(CO)y]2, where M = Mo, Fe and Ni for y = 3, 2 and 1, respectively. The spectral and chemical properties of many of these reduced species are described.

AB - The alkali metal reductions of a series of monomeric and dimeric cyclopentadienyl-substituted metal carbonyls in hexamethylphosphoramide provide principally C5H5V(CO)32- from C5H5V(CO)4, Mn(CO)43- from C5H5Mn(CO)3, Co(CO)4- from C5H5Co(CO)2, and C5H5M(CO)y- from corresponding [C5H5M(CO)y]2, where M = Mo, Fe and Ni for y = 3, 2 and 1, respectively. The spectral and chemical properties of many of these reduced species are described.

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EP - 396

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

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The chemistry of metal carbonyl anions. VII. Reduction of cyclopentadienylmetal carbonyls in hexamethylphosphoramide

Abstract

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