Abstract
The alkali metal reductions of a series of monomeric and dimeric cyclopentadienyl-substituted metal carbonyls in hexamethylphosphoramide provide principally C5H5V(CO)32- from C5H5V(CO)4, Mn(CO)43- from C5H5Mn(CO)3, Co(CO)4- from C5H5Co(CO)2, and C5H5M(CO)y- from corresponding [C5H5M(CO)y]2, where M = Mo, Fe and Ni for y = 3, 2 and 1, respectively. The spectral and chemical properties of many of these reduced species are described.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 389-396 |
| Number of pages | 8 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 120 |
| Issue number | 3 |
| DOIs | |
| State | Published - Nov 9 1976 |
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Ellis, J. E., Faltynek, R. A., & Hentges, S. G. (1976). The chemistry of metal carbonyl anions. VII. Reduction of cyclopentadienylmetal carbonyls in hexamethylphosphoramide. Journal of Organometallic Chemistry, 120(3), 389-396. https://doi.org/10.1016/S0022-328X(00)98050-1