The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru333-CHCHCMe)(CO)9 and its PPh3 derivatives

K. Mohan Rao, Robert J. Angelici, Victor G. Young

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19 Scopus citations

Abstract

Reactions of Ru3(CO)12 with 1,3-butadiene or cis-2-butene give the μ33dimetalloallyl compound (β-H)Ru333-CHCHCMe)(CO)9 (2). Refluxing 2 with PPh3 gives the CO-substituted products (μ-H)Ru33-3 CHCHCMe)(CO)8(PPh3) (3) and (μ3-H)Ru333-CHCHCMe(CO)7(PPh3)2 (4). Single crystal X-ray diffraction studies of 2, 3 and 4 show that all have the dimetalloallyl unit. These investigations demonstrate that this unit is remarkably stable and might be expected to form on triangular arrays of metal atoms on metal surfaces.

Original languageEnglish (US)
Pages (from-to)211-217
Number of pages7
JournalInorganica Chimica Acta
Volume198-200
Issue numberC
DOIs
StatePublished - Jan 1 1992

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