The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 and its PPh3 derivatives

K. Mohan Rao; Robert J. Angelici; Victor G. Young

doi:10.1016/S0020-1693(00)92363-6

The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru₃(μ₃-η³-CHCHCMe)(CO)₉ and its PPh₃ derivatives

K. Mohan Rao, Robert J. Angelici, Victor G. Young

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Reactions of Ru₃(CO)₁₂ with 1,3-butadiene or cis-2-butene give the μ₃-η³dimetalloallyl compound (β-H)Ru₃(β₃-η³-CHCHCMe)(CO)₉ (2). Refluxing 2 with PPh₃ gives the CO-substituted products (μ-H)Ru₃(μ_3--η³ CHCHCMe)(CO)₈(PPh₃) (3) and (μ3-H)Ru₃(μ₃-η³-CHCHCMe(CO)₇(PPh₃)₂ (4). Single crystal X-ray diffraction studies of 2, 3 and 4 show that all have the dimetalloallyl unit. These investigations demonstrate that this unit is remarkably stable and might be expected to form on triangular arrays of metal atoms on metal surfaces.

Original language	English (US)
Pages (from-to)	211-217
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	198-200
Issue number	C
DOIs	https://doi.org/10.1016/S0020-1693(00)92363-6
State	Published - Jan 1 1992

Access

10.1016/S0020-1693(00)92363-6

Fingerprint Dive into the research topics of 'The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 and its PPh3 derivatives'. Together they form a unique fingerprint.

Cite this

@article{28edf9fb57d74ac58ec6bb606e5a7bdd,

title = "The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 and its PPh3 derivatives",

abstract = "Reactions of Ru3(CO)12 with 1,3-butadiene or cis-2-butene give the μ3-η3dimetalloallyl compound (β-H)Ru3(β3-η3-CHCHCMe)(CO)9 (2). Refluxing 2 with PPh3 gives the CO-substituted products (μ-H)Ru3(μ3--η3 CHCHCMe)(CO)8(PPh3) (3) and (μ3-H)Ru3(μ3-η3-CHCHCMe(CO)7(PPh3)2 (4). Single crystal X-ray diffraction studies of 2, 3 and 4 show that all have the dimetalloallyl unit. These investigations demonstrate that this unit is remarkably stable and might be expected to form on triangular arrays of metal atoms on metal surfaces.",

author = "Rao, {K. Mohan} and Angelici, {Robert J.} and Young, {Victor G.}",

year = "1992",

month = jan,

day = "1",

doi = "10.1016/S0020-1693(00)92363-6",

language = "English (US)",

volume = "198-200",

pages = "211--217",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "C",

}

TY - JOUR

T1 - The 1,3-dimetalloallyl tri-ruthenium cluster (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 and its PPh3 derivatives

AU - Rao, K. Mohan

AU - Angelici, Robert J.

AU - Young, Victor G.

PY - 1992/1/1

Y1 - 1992/1/1

N2 - Reactions of Ru3(CO)12 with 1,3-butadiene or cis-2-butene give the μ3-η3dimetalloallyl compound (β-H)Ru3(β3-η3-CHCHCMe)(CO)9 (2). Refluxing 2 with PPh3 gives the CO-substituted products (μ-H)Ru3(μ3--η3 CHCHCMe)(CO)8(PPh3) (3) and (μ3-H)Ru3(μ3-η3-CHCHCMe(CO)7(PPh3)2 (4). Single crystal X-ray diffraction studies of 2, 3 and 4 show that all have the dimetalloallyl unit. These investigations demonstrate that this unit is remarkably stable and might be expected to form on triangular arrays of metal atoms on metal surfaces.

AB - Reactions of Ru3(CO)12 with 1,3-butadiene or cis-2-butene give the μ3-η3dimetalloallyl compound (β-H)Ru3(β3-η3-CHCHCMe)(CO)9 (2). Refluxing 2 with PPh3 gives the CO-substituted products (μ-H)Ru3(μ3--η3 CHCHCMe)(CO)8(PPh3) (3) and (μ3-H)Ru3(μ3-η3-CHCHCMe(CO)7(PPh3)2 (4). Single crystal X-ray diffraction studies of 2, 3 and 4 show that all have the dimetalloallyl unit. These investigations demonstrate that this unit is remarkably stable and might be expected to form on triangular arrays of metal atoms on metal surfaces.

UR - http://www.scopus.com/inward/record.url?scp=0001687142&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001687142&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(00)92363-6

DO - 10.1016/S0020-1693(00)92363-6

M3 - Article

AN - SCOPUS:0001687142

VL - 198-200

SP - 211

EP - 217

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - C

ER -