Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy

Ningxin Jiang; Jan Niklas Boyn; Arun Ramanathan; Henry S. La Pierre; John S. Anderson

doi:10.1039/d3cc02325g

Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy

Ningxin Jiang, Jan Niklas Boyn, Arun Ramanathan, Henry S. La Pierre, John S. Anderson

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Sulfur K-edge XAS data provide a unique tool to examine oxidation states and covalency in electronically complex S-based ligands. We present sulfur K-edge X-ray absorption spectroscopy on a discrete redox-series of Ni-based tetrathiafulvalene tetrathiolate (TTFtt) complexes as well as on a 1D coordination polymer (CP), NiTTFtt. Experiment and theory suggest that Ni-S covalency decreases with oxidation which has implications for charge transport pathways.

Original language	English (US)
Pages (from-to)	9537-9540
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	62
DOIs	https://doi.org/10.1039/d3cc02325g
State	Published - Jun 29 2023
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2023 The Royal Society of Chemistry.

Publisher link

10.1039/d3cc02325g

Find It

Find It at U of M Libraries

Cite this

@article{5f27c58274f44b1e9f0dab55f14593d8,

title = "Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy",

abstract = "Sulfur K-edge XAS data provide a unique tool to examine oxidation states and covalency in electronically complex S-based ligands. We present sulfur K-edge X-ray absorption spectroscopy on a discrete redox-series of Ni-based tetrathiafulvalene tetrathiolate (TTFtt) complexes as well as on a 1D coordination polymer (CP), NiTTFtt. Experiment and theory suggest that Ni-S covalency decreases with oxidation which has implications for charge transport pathways.",

author = "Ningxin Jiang and Boyn, \{Jan Niklas\} and Arun Ramanathan and \{La Pierre\}, \{Henry S.\} and Anderson, \{John S.\}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = jun,

day = "29",

doi = "10.1039/d3cc02325g",

language = "English (US)",

volume = "59",

pages = "9537--9540",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "62",

}

TY - JOUR

T1 - Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy

AU - Jiang, Ningxin

AU - Boyn, Jan Niklas

AU - Ramanathan, Arun

AU - La Pierre, Henry S.

AU - Anderson, John S.

PY - 2023/6/29

Y1 - 2023/6/29

N2 - Sulfur K-edge XAS data provide a unique tool to examine oxidation states and covalency in electronically complex S-based ligands. We present sulfur K-edge X-ray absorption spectroscopy on a discrete redox-series of Ni-based tetrathiafulvalene tetrathiolate (TTFtt) complexes as well as on a 1D coordination polymer (CP), NiTTFtt. Experiment and theory suggest that Ni-S covalency decreases with oxidation which has implications for charge transport pathways.

AB - Sulfur K-edge XAS data provide a unique tool to examine oxidation states and covalency in electronically complex S-based ligands. We present sulfur K-edge X-ray absorption spectroscopy on a discrete redox-series of Ni-based tetrathiafulvalene tetrathiolate (TTFtt) complexes as well as on a 1D coordination polymer (CP), NiTTFtt. Experiment and theory suggest that Ni-S covalency decreases with oxidation which has implications for charge transport pathways.

UR - https://www.scopus.com/pages/publications/85166181751

UR - https://www.scopus.com/inward/citedby.url?scp=85166181751&partnerID=8YFLogxK

U2 - 10.1039/d3cc02325g

DO - 10.1039/d3cc02325g

M3 - Article

C2 - 37458323

AN - SCOPUS:85166181751

SN - 1359-7345

VL - 59

SP - 9537

EP - 9540

JO - Chemical Communications

JF - Chemical Communications

IS - 62

ER -

Tetrathiafulvalene-2,3,6,7-tetrathiolate linker redox-state elucidation via S K-edge X-ray absorption spectroscopy

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this