Tetranuclear nickel(II) complex with tripodal hydroxyl ligand functionalized by additional salicylaldehyde donor pendant: Synthesis, crystal structure and magnetic property

Jing Wen Ran; Su Yun Zhang; Bin Xu; Yuanzhi Xia; Dong Guo; Jing Yan Zhang; Yahong Li

doi:10.1016/j.inoche.2007.10.014

Tetranuclear nickel(II) complex with tripodal hydroxyl ligand functionalized by additional salicylaldehyde donor pendant: Synthesis, crystal structure and magnetic property

Jing Wen Ran, Su Yun Zhang, Bin Xu, Yuanzhi Xia, Dong Guo, Jing Yan Zhang, Yahong Li

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The tetranuclear cubane-like [Ni₄(H₃hbhpd)₄] · 4H₂O complex has been prepared by the reaction of nickel(II) acetate with H₅hbhpd, where H₅hbhpd is 2(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol. The X-ray diffraction analysis of the complex showed a Ni₄O₄ cubane arrangement of four nickel atoms. Magnetic studies indicate ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters are given as g = 2.21, J₁ = 0.32, J₂ = 8.27, D = -0.05 cm^-1.

Original language	English (US)
Pages (from-to)	73-76
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2007.10.014
State	Published - Jan 2008
Externally published	Yes

Bibliographical note

Funding Information:
The authors appreciate the financial supports of Hundreds of Talents Program (2005012) of CAS, Natural Science Foundation of Jiangsu Province (BK2005030) and Natural Science Foundation of Qinghai Province (2006-G-105). The authors thank Professor Song Gao for magnetic measurement assistance.

Keywords

Cubane-like
Magnetic properties
Nickel complex
Tetranuclear

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10.1016/j.inoche.2007.10.014

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@article{f51f4159a9ce4cd0a5c06d9a19c86a08,

title = "Tetranuclear nickel(II) complex with tripodal hydroxyl ligand functionalized by additional salicylaldehyde donor pendant: Synthesis, crystal structure and magnetic property",

abstract = "The tetranuclear cubane-like [Ni4(H3hbhpd)4] · 4H2O complex has been prepared by the reaction of nickel(II) acetate with H5hbhpd, where H5hbhpd is 2(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement of four nickel atoms. Magnetic studies indicate ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters are given as g = 2.21, J1 = 0.32, J2 = 8.27, D = -0.05 cm-1.",

keywords = "Cubane-like, Magnetic properties, Nickel complex, Tetranuclear",

author = "Ran, {Jing Wen} and Zhang, {Su Yun} and Bin Xu and Yuanzhi Xia and Dong Guo and Zhang, {Jing Yan} and Yahong Li",

note = "Funding Information: The authors appreciate the financial supports of Hundreds of Talents Program (2005012) of CAS, Natural Science Foundation of Jiangsu Province (BK2005030) and Natural Science Foundation of Qinghai Province (2006-G-105). The authors thank Professor Song Gao for magnetic measurement assistance. ",

year = "2008",

month = jan,

doi = "10.1016/j.inoche.2007.10.014",

language = "English (US)",

volume = "11",

pages = "73--76",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Tetranuclear nickel(II) complex with tripodal hydroxyl ligand functionalized by additional salicylaldehyde donor pendant

T2 - Synthesis, crystal structure and magnetic property

AU - Ran, Jing Wen

AU - Zhang, Su Yun

AU - Xu, Bin

AU - Xia, Yuanzhi

AU - Guo, Dong

AU - Zhang, Jing Yan

AU - Li, Yahong

N1 - Funding Information: The authors appreciate the financial supports of Hundreds of Talents Program (2005012) of CAS, Natural Science Foundation of Jiangsu Province (BK2005030) and Natural Science Foundation of Qinghai Province (2006-G-105). The authors thank Professor Song Gao for magnetic measurement assistance.

PY - 2008/1

Y1 - 2008/1

N2 - The tetranuclear cubane-like [Ni4(H3hbhpd)4] · 4H2O complex has been prepared by the reaction of nickel(II) acetate with H5hbhpd, where H5hbhpd is 2(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement of four nickel atoms. Magnetic studies indicate ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters are given as g = 2.21, J1 = 0.32, J2 = 8.27, D = -0.05 cm-1.

AB - The tetranuclear cubane-like [Ni4(H3hbhpd)4] · 4H2O complex has been prepared by the reaction of nickel(II) acetate with H5hbhpd, where H5hbhpd is 2(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement of four nickel atoms. Magnetic studies indicate ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters are given as g = 2.21, J1 = 0.32, J2 = 8.27, D = -0.05 cm-1.

KW - Cubane-like

KW - Magnetic properties

KW - Nickel complex

KW - Tetranuclear

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DO - 10.1016/j.inoche.2007.10.014

M3 - Article

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SN - 1387-7003

VL - 11

SP - 73

EP - 76

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

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Tetranuclear nickel(II) complex with tripodal hydroxyl ligand functionalized by additional salicylaldehyde donor pendant: Synthesis, crystal structure and magnetic property

Abstract

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Keywords

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