Tetrakis(tetrabutylammonium) tetrakis-[(p-cyanophenyl)trioxoarsonato]-tetratriacontaoxododecamolybdate(4-)

Bret J.S. Johnson; Carrie E. Buss; Victor G. Young; Andreas Stein

doi:10.1107/S0108270198017636

Tetrakis(tetrabutylammonium) tetrakis-[(p-cyanophenyl)trioxoarsonato]-tetratriacontaoxododecamolybdate(4-)

Bret J.S. Johnson, Carrie E. Buss, Victor G. Young, Andreas Stein

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Crystals of the title compound, (C₁₆H₃₆N)₄[(p-NC-C₆H ₄As)₄MO₁₂O₄₆] or (C₁₆H₃₆N)₄[{As(C₇H ₄N)}₄Mo₁₂-O₄₆], were synthesized by the reaction of p-cyanophenylarsonic acid and sodium molybdate at low pH. With nitrile groups pointed in tetrahedral directions, these new organically modified polyoxometalate clusters are potential building blocks in coordination networks.

Original language	English (US)
Pages (from-to)	549-551
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Issue number	4
DOIs	https://doi.org/10.1107/S0108270198017636
State	Published - Apr 15 1999

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@article{a853036b5b6f469bb5319fc0e4f75fc6,

title = "Tetrakis(tetrabutylammonium) tetrakis-[(p-cyanophenyl)trioxoarsonato]-tetratriacontaoxododecamolybdate(4-)",

abstract = "Crystals of the title compound, (C16H36N)4[(p-NC-C6H 4As)4MO12O46] or (C16H36N)4[\{As(C7H 4N)\}4Mo12-O46], were synthesized by the reaction of p-cyanophenylarsonic acid and sodium molybdate at low pH. With nitrile groups pointed in tetrahedral directions, these new organically modified polyoxometalate clusters are potential building blocks in coordination networks.",

author = "Johnson, \{Bret J.S.\} and Buss, \{Carrie E.\} and Young, \{Victor G.\} and Andreas Stein",

year = "1999",

month = apr,

day = "15",

doi = "10.1107/S0108270198017636",

language = "English (US)",

volume = "55",

pages = "549--551",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "4",

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TY - JOUR

T1 - Tetrakis(tetrabutylammonium) tetrakis-[(p-cyanophenyl)trioxoarsonato]-tetratriacontaoxododecamolybdate(4-)

AU - Johnson, Bret J.S.

AU - Buss, Carrie E.

AU - Young, Victor G.

AU - Stein, Andreas

PY - 1999/4/15

Y1 - 1999/4/15

N2 - Crystals of the title compound, (C16H36N)4[(p-NC-C6H 4As)4MO12O46] or (C16H36N)4[{As(C7H 4N)}4Mo12-O46], were synthesized by the reaction of p-cyanophenylarsonic acid and sodium molybdate at low pH. With nitrile groups pointed in tetrahedral directions, these new organically modified polyoxometalate clusters are potential building blocks in coordination networks.

AB - Crystals of the title compound, (C16H36N)4[(p-NC-C6H 4As)4MO12O46] or (C16H36N)4[{As(C7H 4N)}4Mo12-O46], were synthesized by the reaction of p-cyanophenylarsonic acid and sodium molybdate at low pH. With nitrile groups pointed in tetrahedral directions, these new organically modified polyoxometalate clusters are potential building blocks in coordination networks.

UR - https://www.scopus.com/pages/publications/0348225539

UR - https://www.scopus.com/inward/citedby.url?scp=0348225539&partnerID=8YFLogxK

U2 - 10.1107/S0108270198017636

DO - 10.1107/S0108270198017636

M3 - Article

AN - SCOPUS:0348225539

SN - 0108-2701

VL - 55

SP - 549

EP - 551

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 4

ER -

Tetrakis(tetrabutylammonium) tetrakis-[(p-cyanophenyl)trioxoarsonato]-tetratriacontaoxododecamolybdate(4-)

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