Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone

Yukino Shinomoto; Akira Yoshimura; Hisato Shimizu; Mutsumi Yamazaki; Viktor V. Zhdankin; Akio Saito

doi:10.1021/acs.orglett.5b02543

Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone

Yukino Shinomoto, Akira Yoshimura, Hisato Shimizu, Mutsumi Yamazaki, Viktor V. Zhdankin, Akio Saito

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.

Original language	English (US)
Pages (from-to)	5212-5215
Number of pages	4
Journal	Organic Letters
Volume	17
Issue number	21
DOIs	https://doi.org/10.1021/acs.orglett.5b02543
State	Published - Nov 6 2015

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title = "Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone",

abstract = "Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.",

author = "Yukino Shinomoto and Akira Yoshimura and Hisato Shimizu and Mutsumi Yamazaki and Zhdankin, {Viktor V.} and Akio Saito",

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AU - Shinomoto, Yukino

AU - Yoshimura, Akira

AU - Shimizu, Hisato

AU - Yamazaki, Mutsumi

AU - Zhdankin, Viktor V.

AU - Saito, Akio

PY - 2015/11/6

Y1 - 2015/11/6

N2 - Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.

AB - Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.

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