Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

Nyasha Kanganga; Kent R. Mann; Daron E. Janzen

doi:10.1107/S1600536808036726

Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

Nyasha Kanganga
, Kent R. Mann
, Daron E. Janzen

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, (C16H36N)2[Pt(C4N2S2)2], the Pt^II center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

Original language	English (US)
Pages (from-to)	m1552
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	12
DOIs	https://doi.org/10.1107/S1600536808036726
State	Published - 2008

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10.1107/S1600536808036726

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title = "Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)",

abstract = "In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.",

author = "Nyasha Kanganga and Mann, \{Kent R.\} and Janzen, \{Daron E.\}",

year = "2008",

doi = "10.1107/S1600536808036726",

language = "English (US)",

volume = "64",

pages = "m1552",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

AU - Kanganga, Nyasha

AU - Mann, Kent R.

AU - Janzen, Daron E.

PY - 2008

Y1 - 2008

N2 - In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

AB - In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol- ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

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UR - https://www.scopus.com/pages/publications/57349118460#tab=citedBy

U2 - 10.1107/S1600536808036726

DO - 10.1107/S1600536808036726

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SP - m1552

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Tetra-n-butyl-ammonium bis-(1,1-dicyano-ethyl-ene-2,2-dithiol-ato) platinum(II)

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