TEMPO-catalyzed aerobic oxygenation and nitrogenation of olefins via C=C double-bond cleavage

Teng Wang, Ning Jiao

Research output: Contribution to journalArticlepeer-review

147 Scopus citations

Abstract

A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via C=C double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.

Original languageEnglish (US)
Pages (from-to)11692-11695
Number of pages4
JournalJournal of the American Chemical Society
Volume135
Issue number32
DOIs
StatePublished - Aug 14 2013

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