We present a techno-economic analysis of a 17,000–18,000 metric tons per year electrolytic process for producing Mg from MgO with and without out a concentrated solar thermal input. The solar thermal input is delivered via power tower technology and the evaporation and condensation of sodium. Energy requirements for the process at scale were based on thermodynamics and an extrapolation of laboratory measurements of the electrochemical kinetic and mass transport parameters via a finite-element numerical model. While technically possible, integrating a solar thermal input does not make economic sense without crediting avoided CO2 emissions. A solar thermal input reduces energy operational costs from $0.654/kg to as low as $ 0.481/kg, but it also lowers the Mg production rate of the electrolytic cells such that more cells are required to achieve production capacity, which, in turn, increases capital and maintenance costs. The net operational savings are negligible. The estimated operational costs to produce Mg are ∼$2.46/kg. At this cost, the process without a solar thermal input is economically tantalizing vis à vis the current commercial processes for producing Mg, and its CO2 emission level is 46% lower than that of the Pidgeon process, currently the predominant method for producing Mg.
Bibliographical noteFunding Information:
We are grateful to the U.S. Department of Energy ARPA?E program for financial support for this work under the cooperative agreement DE?AR0000421 and to the Slovak Research and Development Agency under the contract APVV?15?0738. We are further grateful to Dr. Scott Duncan (Valparaiso University) for his important contributions to the economic and manufacturing aspects of this work.
© 2017 Elsevier Ltd
- Magnesium electrolysis
- Molten salts
- Sodium heat pipes
- Solar thermal chemistry
- Thermal electrolytic process