Synthetic, structural, spectroscopic and theoretical study of a Mn(iii)-Cu(ii) dimer containing a Jahn-Teller compressed Mn ion

Keyphrases

• 2,2′-biphenol 33%
• Anisotropy 100%
• Antiferromagnetic Exchange 66%
• Antiferromagnetic Interaction 33%
• Cu(II) 100%
• CuMn 33%
• DFT Calculations 33%
• Ethanol 33%
• Heterobimetallic Complexes 33%
• High Field 66%
• Ion Cluster 33%
• Jahn-Teller 100%
• Large-scale Cluster 33%
• Low Temperature 33%
• Magnetic Susceptibility Measurement 33%
• Magnetization Measurements 33%
• Mn Ions 100%
• O Atom 33%
• Orbital Mixing 33%
• Phenolate 33%
• Rare Example 33%
• Single-ion Anisotropy 100%
• Spin-orbit Coupling 33%
• Temperature Field 33%

Chemistry

• Anisotropy 100%
• Antiferromagnetic 16%
• Antiferromagnetic Exchange 33%
• Density Functional Theory 16%
• dimer 100%
• EPR Spectroscopy 16%
• Magnetic Susceptibility Measurement 16%
• Phenolate 16%